蒙脱土对聚羧酸超塑化剂的吸附行为.pdfVIP

第 15卷第4期 蝇 巩 研 科 做 VO1．10， O．4 学兔兔 AL培．，2012 2012年8月 J0URNAI 0F BUILDING MATERIALS 文章编号：1007—9629(2012)04—0464—05 蒙脱土对聚羧酸超塑化剂的吸附行为 杨 勇， 冉千平， 毛永琳， 张志勇 ’ 刘加平 (江苏省建筑科学研究院有限公司 高性能土木工程材料国家重点实验室，江苏 南京 210008) 摘要：测定了蒙脱土对聚羧酸超塑化剂(PCE)分散性能的影响，研究了蒸馏水和水泥滤液中蒙脱 土对PCE的静态吸附和动态吸附行为，拟合了吸附过程的动力学模型．结果表明：水泥中掺入蒙脱 土会导致PCE对水泥分散能力的显著降低；蒙脱土对PCE的吸附量与PCE质量浓度近似成正比 关系；水泥滤液中，PCE在蒙脱土上的平衡吸附量要远高于蒸馏水中的平衡吸附量；PCE在蒙脱土 上的吸附过程均符合准二级反应动力学模型． 关键词：聚羧酸超塑化剂；蒙脱土；分散性能；吸附 中图分类号：TU528．042．2 文献标志码：A doi：10．3969／j．issn．1007—9629．2012．04．005 Adsorption Behavior of P0lycarb0xylate Superplasticizers onto Montmorillonite YANG Yong， RAN Qian—ping， MAO Yong—lin， ZHANG Zhi—yong， LIU Jia ping (State Key Laboratory of High Performance Civil Engineering Materials，J iangsu Institute of Building Science Co．，Ltd．， Nanjing 210008，China) Abstract：The effect of montmorillonite(MMT)on the dispersion properties of polycarboxylate superplas— ticizers(PCE)was investigated．The static and dynamic adsorption behaviors of PCE onto MMT in dis— tilled water and cement filtrate were studied respectively．The results show that adding the MMT into ce— ment could significantly decrease the dispersion properties of PCE．The amount of PCE adsorbed onto MMT is roughly directly proportional to the mass concentrations of PCE．The saturation amount of PCE adsorbed onto MMT in cement filtrate is much higher than that in distilled water，and the adsorption process could be well described using pseudo—second—order reaction kinetics mode1．