高保坍型聚羧酸减水剂的合成及性能表征.pdfVIP

学兔兔 钎 建魄 中国科技核心期刊 高保坍型聚羧酸减水剂的合成 及性能表征 郭清春，周普玉，杨霞 (上海市建筑科学研究院，上海 201 108) 摘要：研制了一种高保坍型聚羧酸减水剂，可以在炎热环境下使用，具有减水率高、保坍性好等优势。通过Pc—M与不同水泥 的适应性研究、混凝土保坍性试验、吸附量以及Zeta电位的研究，结果表明：n(AA)：n(T)=5：1时，得到的聚羧酸减水剂Pc—M性能 最优；Pc—M掺量为0，2％时，混凝土1 h坍落度保持率为97．8％；对于不同种类的水泥，吸附量是聚羧酸减水剂发挥分散作用的一个 前提，但并不是吸附量越大对水泥的塑化效果越好；PC—M是以空间位阻而不是静电斥力为主要作用发挥其分散的特性。 关键词：聚羧酸减水剂；分散性能；保坍性能；吸附量；Zeta电位 中图分类号：TU528．042．2 文献标识码：A 文章编号：1001—702X(2014)02—0009—04 Research on synthesis and characterization of high slump retention superplasticizer GUO Qingchun，ZHOU Puyu，YANG Xia ‘ (Shanghai Research Institute of Building Science，Shanghai 201 108，China) Abstract：A high slump retention superplasticizer with high water reduction and high slump retention is developed，which Call be used in hot environment．This study investigated the adaptability between PC—M and different types of cement，concrete slump， adsorption and zeta potentia1．The results indicated that PC-M has the best performance at n(AA)：n(T)=5：1，when the PC-M con- tent is O．2％，1 h concrete slump retention rate is 97．8％．For different types of cement，the adsorption amount of polyearboxylate plays the role of a premise of dispersion，but not greater adsorption capacity，the better the plasticizing effect of the cement．PC-M plays the role of dispersion mainly on the basis of steric hindrance rather than electrostatic repulsion． Key words：polycarboxylate superplasticizer：dispersing ability：slump r