具有液-液相分离性质的Bi60Ga40合金熔体黏滞性的研究.pdfVIP

学兔兔 Feb．2009 铸 造 VoI．58 N0．2 FOUNDRY ·113· 具有液一液相分离性质的Bi6oGa∞合金熔体 黏滞性的研究 李祯元 ，耿浩然 ，王致明 ，刘建同 (1．济南大学材料科学与工程学院，山东济南250022；2．山东大学材料科学与工程学院，山东济南250061) 摘要：通过对Bi6oGa4o合金熔体的黏度的系统测量和分析，研究了Bi6oGa4o合金熔体的黏度随温度变化的规律和熔体结构 的变化。结果表明，Bi a40合金熔体的黏度随温度的变化呈明显的不连续性，根据黏度的变化可以将熔体状态分为高 温区、中温区和低温区，各温区间存在黏度突变温度区间。DSC进一步验证了Bi6oGa,o)~体在620~650℃之间发生了结构 突变，在260～290℃之间由于液．液相分离引起了结构突变。文中对试验结果进行了讨论。 关键词：Bi6oGa40合金；黏度；液．液相分离；熔体结构 中图分类号：TG146．1 文献标识码：A 文章编号：1001—4977(2009)02—0113—04 Study on Viscosity of Immiscible Liquid Bi60Ga4o Alloy LI Zhen．yuan1，GENG Hao．ran1，WANG Zhi—ming ，LIU Jian-tong (1．College of Material Science and Engineering，University of Jinan，Ji。nan 250022，Shandong，China； 2．College of Material Science and Engineering，Shandong University，Ji。nan 250061，Shandong，China) Abstract：The temperature dependence of viscosity of liquid Bi60Ga40 alloy has been measured using torsionaI oscillation viscosity measurement．The results show that the change of viscosity with temperature iS distinctly discontinuous，which can be divided into three parts：the changes in high ternperature region，mid—temperature region，as well as Iow temperature region．In these different regions，the structures of melt are distinct．The appearance of exothermic peaks on DSC curve during cooling process further proved the structure changes of melt in 620-650℃．The liquid-liquid phase separation iS naturally accompanied with structure change of melt in 260—290℃．which iS also reflected by the discOntinuOus change of viscosity and DSC analysis． Key words：B~Ga4o alloy；viscosity；liquid—liquid phase segregation；melt structure 众所周知，固态结晶物质在一定的温度、压力下