三峡库区消落带甲基汞变化特征的模拟.pdfVIP

中国环境科学 2014.34(2): 499-504 China Environmental Science 三峡库区消落带甲基宗变化特征的模拟 张 成 12，宋 丽 1 ，王定勇 l 气孙荣国 1 ，张金洋 l (l西南大学资源环境学院，重庆 400715;2重庆市农业资源 与环境研究重点实验室，重庆 400715) 摘要3 为探寻三峡水库消落帝在干湿交替条件下甲基柔的变化规律，以库区典型消落带士攘为研究对象，采用模拟试验，研究了干湿交替条 件下消落带土壤和水体甲基示含量和动态变化趋势及其影响因素.结果表明:淹水过程会促进土壤无机示向有机录转化，土壤甲基示含量在 淹水和落干过程均呈现先增加后减少的趋势;随着干湿交替周期的增加，土壤甲基示含量增加，第二次淹水后土壤甲基京平均含量比第一次 淹水增加了22.13%，第二次落干后土壤甲基柔平均含量比第一次落干增加了 58.1 7%.第二次淹水过程土壤甲基录占总录的比例明显高于第 一次淹水，土壤中柔的甲基化主要与干湿交替循环有关土壤淹水后会迅速向水体释放甲基泵，水体中甲基:7R含量明显增加，两次淹水过程 增幅分别为 11 9.42%和 334.72%，水体甲基柔和土壤甲基隶之间无显著相关.干湿交替环境土壤甲基:7R含量主要受pH 值、有机质含量、 Eh 和土壤含水量等因素的影响;水体中甲基:7R含量的影响因素则主要有水体pH 值、 DO、 DOM、水温等. 关键词:三峡库区:消落带:甲基柔g 干湿交替 中图分类号: X131 文献标识码:A 文章编号: 1000-6923(2014)02-0499-06 Simulation on the variation characteristics of methylmercuηof the water-Ievel-ßuctua伽g zone in the Three Gorges l l Area. ZHANG Cheng ,2, SONG Li I, WANG Ding-yong ,2, SUN Rong-酬。I， ZHANG Jin-y缸19l (1.College of Resour回咀 and Environment, Southwest University, Chongqing 400715 , China; 2.Chongqing Key Laboratocy of Agricultural Resour四s and Environment, Chongqing 400715 , China). China Environmental Science, 2014 ,34(2): 499-504 Abstract: To investigate variation of methylmercUI) of the water-level-fluctuating zone in the Three Gorges Reservoir Area, dynamic changes of methylmercUI) contents and influencing factors were analyzed in soil and water by simulation experiment. The results showed that the methylmercUI) contents in soil initially increased but then decreased in bo伯伯e flooding and dcying pr。因ss. Flooding could promote the transformation of inorganic mercUI) into organic forms. MethylmercUI) contents in soil increased with the number of wet-dcy cycles. The average me也ylmercUI) content in soil during the second flooding phase was 22.13% higher than the flfst one, whereas