CO甲烷化Ni基催化剂的研究进展-学兔兔 www.xuetutu.com.pdfVIP

学兔兔 石 油 化 工 · 340· PETROCHEMICAL TECHN0L0GY 2010年第39卷第3期 饥 。 i进展与述评i 气 ‘ CO甲烷化Ni基催化剂的研究进展 路 霞，陈世恒，王万丽，马紫峰 (上海交通大学化工系，上海 200240) [摘要]综述了国内外CO甲烷化催化剂的研究现状，重点介绍了CO甲烷化Ni基催化剂的载体、助剂和催化机理等方面的研究 进展。关于载体的研究由A1 O 转向ZrO ，助剂从碱土金属和稀土金属向过渡金属元素转变，并在催化机理的研究中引入密度 泛函理论，考察反应过程中生成的活性中间物种对催化活性的影响，以期改进这类催化剂，促进其工业应用。以新型载体负载Fe 等多金属催化剂将是未来CO甲烷化催化剂发展的新方向。 [关键词]镍基催化刹；一氧化碳甲烷化；载体；催化机理 [文章编号]1000—8144(2010)03—0341—06 [中图分类号]TQ 032 [文献标识码]A Progress in Ni-Based Catalysts for CO Methanation Lu Xia，Chen Shiheng，Wang Wanli，Ma Zifeng (Department of Chemical Engineering，Shanghm Jiao Tong University，Shanghai 200240，China) [Abstract]Ni—based catalysts for CO methanation were introduced，especially focused on supports， promoters and catalysis mechanism．It was found that ZrO2 was used as support instead of A12 O3， while the promoters covered not only alkaline earth，lanthanon but also transition metals．As to the catalytic mechanism，density functional theory was introduced to investigate effect of intermediate species on activities of the catalysts．In conclusion，multi—metal catalysts such as Fe—Ni alloy supported on novel support are a prospective subject for CO methanation． [Keywords]nickel—based catalyst；carbon monoxide methanation；support；catalytic mechanism 由于石油资源日趋紧张，作为生产替代石油资 应用前景的CO甲烷化催化剂主要是Ru基催化 源的重要手段，基于Fischer—Tropsch合成反应的 剂和Ni基催化剂，Ru基催化剂比Ni基催化剂的 煤炭清洁转化技术吸引了世界能源巨头和学术界