混合丁烷在Cr／Al2O3催化剂上的脱氢性能-学兔兔 www.xuetutu.com.pdfVIP

学兔兔 石 油 化 工 2015年第44卷第12期 PETR0CHEMICAL TECHN0LoGY ·1461· 混合丁烷在Cr／AI2O3催化剂上的脱氢性能 张梨梅，房德仁，任万忠，刘 尚 (烟台大学 山东省石化轻烃综合利用工程技术中心，山东 烟台 264005) [摘要]PACr／A1 O 为催化剂催化混合丁烷脱氢，采用SEM技术对催化剂进行表征，考察了反应温度和液时空速对混合丁烷脱 氢性能的影响，并分析了正丁烷脱氢反应的产物分布。表征结果显示，Cr／A1 O 具有较好的球形形态，粒径36～135 um。实 验结果表明，Cr／A120，对混合丁烷脱氢具有较高的催化活性，在反应温度540℃、液时空速2．5 h-1时，100％(w)正丁烷的转化 率达30％以上，正丁烯选择性接近80％；在反应温度540 oC、液时空速2．5 h-I时，混合丁烷中正丁烷含量(W)为40％～100％时 的转化率达30％以上，丁烯选择性达90％以上；在反应温度540～560℃、液时空速2．0～2．5 h-l时，混合丁烷中正丁烷含量低 于40％(W)时的转化率为33％～45％，丁烯选择性达90％以上。正丁烷脱氢反应产物中反丁烯的选择性最高，顺丁烯次之，1一 丁烯最低。 [关键词]铬／氧化铝催化剂；混合丁烷；脱氢；丁烯 [文章编号]1000—8144(2015)12—1461—06 [中图分类号]TQ 426．83 [文献标志码]A DehydrOgenation of Mixed Butanes over Cr／AI2O3 Catalyst ZhangLimei，FangDeren，Ren Wanzhong，Liu Shang (Light Hydrocarbon Comprehensive Utilization Engineering Center，Yantai University，Yantai Shandong 264005，China) l Abstract J The dehydrogenation of mixed butanes over the Cr／A1，O catalyst was studied．The effects of reaction temperature and liquid hourly space velocity(LHSV)on the dehydrogenation were investigated and the product distribution was analyzed．The result indicated that Cr／A12O3 had good spherical morphology，particle size is 36-135肛m．The results showed that the Cr／A12O3 catalyst had high catalytic activity in the dehydrogenation．When the feedstock was l OO~(w)n-butane，under the optimal conditions of reaction temperature 540℃ and LHSV 2．5 h～．the conversion of n—butane was more than 30％ and the selectivity to n—butene was close to 80％．When the n—butane content in the mixed butanes was in the range of 40％(w