萃取精馏分离环氧丙烷-水-甲醇混合物的模拟-学兔兔 www.xuetutu.com.pdfVIP

学兔兔 石 油 化 工 2013年第42卷第7期 PETROCHEMICAL TeCHN0LOGY ·775· 萃取精馏分离环氧丙烷一水一甲醇混合物的模拟 胡 松，杨卫胜 (中国石化 上海石油化工研究院，上海 201208) [摘要]采用化工流程模拟软件Aspen Plus，以NRTL模型计算气液平衡，对萃取精馏分离环氧丙烷一水一甲醇混合物的过程进 行模拟。选择1，2-丙二醇为萃取剂，考察了萃取剂与原料的质量比(溶剂比)、萃取精馏塔理论塔板数、粗环氧丙烷进料位 置、萃取剂进料位置、萃取剂进料温度和回流比对分离效果的影响。模拟结果表明，在满足环氧丙烷产品纯度为99．99％(W) 的条件下，优化的工艺条件为：溶剂比O．45，萃取精馏塔理论塔板数30块，粗环氧丙烷进料位置第2O块塔板，萃取剂进料位 置第5块塔板，萃取剂进料温度45℃，回流比0．14。在此工艺条件下，环氧丙烷回收率为99．99％，单位产品热负荷为0．936 GJ／t。 [关键词]环氧丙烷；甲醇；水；丙二醇；萃取精馏；流程模拟；Aspen Plus软件 [文章编号]1000—8144(2013)07—0775—05 [中图分类号]TQ 028 [文献标志码]A Simulation of Separating Propylene Oxide--Water--Methanol Mixture by Extractive Distillation Hu Song，Yang Weisheng (SINOPEC ShanghaiResearchInstitute ofPetrochemicalTechnology，Shanghai 201208，China) 【Abstract J An extractive distillation process with two columns and propylene glycol(PG)as the extractant for separating propylene oxide(PO)·-water--methanol mixture was simulated by using Aspen Plus process simulation software and NRTL mode1．The effects of maj or design parameters，such as mass ratio of extractant and feed(solvent ratio)，theoretical tray number of extractive distillation column，crude PO feeding position and extractant feeding position， extractant feeding temperature and reflux ratio，on the separation were investigated．Aimed at PO mass fraction of 99．99％rw in the product，the optimal process conditions were solvent ratio of 0．45．theoretical tray number of extractive distillation column of 30，crude PO feeding position of the 20恤tray，extractant feeding position of the 5 tray，extractant feeding