高效负载型季鏻盐催化合成碳酸乙烯酯-学兔兔 www.xuetutu.com.pdfVIP

学兔兔 石 油 化 工 2013年第42卷第6期 PETR0CHEMICAL TECHN0L0GY ·671· 高效负载型季鳞盐催化合成碳酸乙烯酯 陈梁锋，肖 含，何文军，杨为民 (中国石化 上海石油化工研究院，上海 201208) [摘要]用沸点较高的Ⅳ，Ⅳ一二甲基甲酰胺(DMF)取代甲苯作为溶剂高效合成了负载型季鳞盐催化剂，并将该催化剂用于环 氧乙烷(EO)与CO，合成碳酸乙烯酯(EC)。对催化剂载体、季鳞盐离子和配位阴离子的种类进行了筛选，优化了合成EC的 工艺条件，并考察了催化剂的重复使用性能。实验结果表明，适宜的催化剂制备条件为：氯甲基化的聚苯乙烯作为催化剂载 体，三苯基膦作为合成季鳞盐的叔膦，DMF作为溶剂，I‘作为配位阴离子；该催化剂用于合成EC的最佳工艺条件为：EO与催 化剂的质量比6．6，反应温度1O0 oC，反应压力2．5 MPa，反应时间2 h；在该条件下，EO转化率为98．4％，EC选择性为99．6％； 催化剂重复使用5次活性无明显下降，显示了良好的工业应用前景。 [关键词]二氧化碳；环氧乙烷；碳酸乙烯酯；负载型季鳞盐催化剂 [文章编号]1000—8144(2013)06—0671—05 [中图分类号]TQ 225．24 [文献标志码]A Highly Efficient Supported Phosphonium Catalysts for the Synthesis of Ethylene Carbonate Chen Liangfeng，Xiao Han，He Wenjun， 馏Weimin (SINOPEC Shanghai Research Institute ofPetrochemical Technology，Shanghai 201208，China) l Abstract]Supported quaternary phosphonium catalysts were prepared with N，N-dimethyl formamide(DMF)as the solvent，which replaced toluene due to its higher boiling point，and used in the synthesis of ethylene carbonate(EC)from ethylene oxide(EO)and CO2．The effects of supports，quaternary phosphonium ions and coordinating anions on the performances of the catalysts were investigated．It was found that the appropriate conditions for the catalyst preparation were chloromethylated polystyrene as the support，tripheny1phOsphine as the tertiary phosphine source， DMF as the solvent and I‘as the coordinating anion．Under the optimized reaction conditions of the mass ratio of EO to the catalyst 6．6，100℃，2．5 MPa and 2 h，the conversion of EO and the selectivity to EC can reach 98．4