轻烃分馏装置液化气胺法脱硫工艺存在问题及解决措施研究.pdfVIP

学兔兔学兔兔 石 油 与 天 然 气 化 工 第 42卷 第 1期 CHEMICAL ENGINEERING OF OIL＆ GAS 15 轻烃分馏装置液化气胺法脱硫工艺 存在问题及解决措施研究 王 国强 (大庆油田化工有限公司轻烃分馏分公司) 摘 要 对轻烃分馏装置的液化气胺法脱硫装置无法长周期稳定运行问题进行了分析，发现 主要原因是胺液发泡和液化气铜片腐蚀不达标。本文针对这两个主要原因进行了详细分析，通过 分析得出：引起胺液发泡的主要原因是脱硫系统脏、液化气含甲醇、胺液降解导致热稳定盐积聚、操 作波动；导致脱硫后液化气铜片腐蚀不达标原因是胺液夹带进入液化气、液化气产品中存在一定量 的有机硫和单质硫未脱除。同时，针对存在的问题提出了相应的解决措施。 关键词 胺液发泡 液化气铜腐 热稳定盐 有机硫 中图分类号：TE644 文献标志码：B DOI：10．3969／i．issn．1007—3426．2013．01．003 Problems and solutions of LPG desulfurization process by amine in the light hydrocarbon fractionation unit Wang Guoqiang (Light hydrocarbon fractionation Branch of Daqing Oi eld Chemical Company Limited，Daqing 163411，HeilongJiang，China) Abstract：Reasons causing the instability for long—term operation of liquefied gas amine desul— furization in the light hydrocarbon fractionation unit were investigated．It was determined that the amine foaming and LPG copper corrosion below the standard cause the instability．The effects of the two critical factors were studied in details in this paper．The analysis showed that the a— mine foaming resu lted from the dirtiness of desulfurization system，LPG containing methanol， the aceumulation of the salt with high heat—stability and operation fluctuation．The copper corro— sion of LPG below the standard resulted from amine entering LPG and a certain amount O{organ— ic suIfur and elemental sulfur not being removed from LPG．According to the analysis of the cau— ses，the corres