离子导体-2.ppt

* 耦合模型的應用 20(Li2O-Cs2O)-15Ga2O3-65GeO2 glasses Mixed alkali effect * The coupling model attributes the mixed alkali effect to mutual interception of jump paths of both kinds of mobile ions . Various experimental techniques have shown that there is a large local site energy difference between two different alkali ions in the mixed alkali glasses. Therefore, jumping of an alkali ion to the sites for a different alkali ion cannot occur. It follows that there are fewer sites for ionic motion of the host alkali species when different alkali ion is introduced. This will immobilize both different al