稀土掺杂量子剪裁和上转换发光材料的制备及应用进展-化工学报.PDF

第 65 卷 第 7 期 化 工 学 报 Vol.65 No.7 July 2014 2014 年 7 月 CIESC Journal ·2620 · 稀土掺杂量子剪裁和上转换发光材料的制备及应用进展 孙容瑾，邱培宇，张春雷，高国，崔大祥 （上海交通大学电子信息与电气工程学院仪器科学与工程系，薄膜与微细技术教育部重点实验室， 纳米生物医学工程研究所，上海 200240 ） 摘要：稀土元素特殊的电子构型，使其具有优异的光性能，成为新的发光材料的宝库。在照明显示、分析检测等 领域，稀土发光材料近年来已经得到了广泛的应用。而且也有多种不同的稀土发光材料问世，如稀土长余辉发光 材料和稀土配合物发光材料等。重点介绍了两种新型的稀土发光材料：拥有高效下转换发光效率的稀土掺杂“量 子剪裁”发光材料和在生物医学领域有着巨大潜力的稀土掺杂“上转换”发光纳米晶体。对两种发光材料的发光 机理进行了描述，并重点展示了两种材料的制备和应用进展。 关键词：稀土；发光；量子剪裁；上转换 DOI ：10.3969/j.issn.0438-1157.2014.07.021 中图分类号：TG 146.4 文献标志码：A 文章编号：0438—1157 （2014 ）07—2620—09 Progress of preparation and application of rare earth luminescent materials SUN Rongjin, QIU Peiyu, ZHANG Chunlei, GAO Guo, CUI Daxiang （Institute of Nano Biomedicine and Engineering, Key Laboratory for Thin Film and Microfabrication Technology of Ministry of Education, Department of Instrument Science and Engineering, School of Electrical Information and Electrical Engineering, Shanghai Jiao Tong University, Shanghai 200240, China ） Abstract: Due to their special electronic configurations, rare earth elements have excellent optical properties, which make them a treasure of new luminescent materials. Recently, in the lighting, display, analysis, testing and other areas, rare earth luminescent materials have been widely used. The knowledge gained thus far has allowed the development of various rare earth luminescent materials, such as rare earth long after-glow phosphors and rare earth complexe