醇对疏水缔合羟乙基纤维素水溶液黏度和表面张力的影响.pdfVIP

学兔兔 石 油 化 工 2011年第40卷第5期 PETROCHEMICAL TECHNOL0GY ·527· 醇对疏水缔合羟乙基纤维素水溶液黏度和 表面张力的影响 王彦玲，仇东旭，赵修太，宋 丽 (中国石油大学(华东)石油工程学院，山东 青岛 266555) [摘要]研究了正丁醇、正辛醇、十二醇对疏水缔合羟乙基纤维素(BHEC)水溶液表观黏度的影响以及乙醇、正丁醇、乙二醇、 1，2一丙二醇对BHEC水溶液表面张力的影响。实验结果表明，醇的加入，有助于提高BHEC水溶液的增黏效果，且醇的碳原子数 越大，BHEC水溶液表观黏度的增幅越大；对于同一种醇，BHEC水溶液质量浓度较高(6 g／L)时，醇对其表观黏度的影响大于 BHEC水溶液质量浓度较低(4 g／L)时；一元醇能降低BHEC水溶液的表面张力，二元醇能略微提高BHEC水溶液的表面张力，且 醇的碳原子数越大，醇对BHEC水溶液表面张力的影响越明显。 [关键词]疏水缔合羟乙基纤维素；醇；表观黏度；表面张力 [文章编号]1000—8144(2011)05—0527—05 [中图分类号]TQ 317．3 [文献标识码]A The Effects of Alcohol on the Viscosity and Surface Tension of Hydroph0bicalIy Modified Hydroxyethyl Cellulose Wang Yanling，Qiu Dongxu，Zhao Xiutai，Song Li (Petroleum Engineering College，Petroleum University of China(Huadong)，Qingdao Shandong 266555，China) [Abstract] The effects of butanol，octanol and dodecanol on the apparent viscosity of hydrophobically modified hydroxyethyl cellulose(BHEC)aqueous solution and the effects of ethanol， butanol，ethylene glycol and 1，2-propylene glycol on its surface tension were studied．The results showed that the alcohols were helpful to improve the tackability of BHEC aqueous solution，and its apparent viscosity increased obviously along with extend of the alcohol carbon chain．For the same alcohol，the apparent viscosity of higher BHEC concentration(6 g／L)solution was affected by the alcohol more than that of lower BHEC concentration(4 g／L)solution；monohydric alcohols reduced the surface tension of BHEC aqueous solutions whereas diol slightly enhanced the surface tensi