纳米镍晶的制备及其在基础油中的摩擦学性能.pdfVIP

学兔兔 石 油 化 工 · 614· PETR0CHEMICAL TeCHN0L0GY 2011年第40卷第6期 纳米镍晶的制备及其在基础油中的摩擦学性能 钱建华，阴翔宇，许家胜 (渤海大学辽宁省功能化合物的合成与应用重点实验室，辽宁锦州121003) [摘要]在水热条件下，以口一环糊精为修饰剂、水合肼为还原剂，还原二水合乙酰丙酮镍前体制备了海绵状纳米镍晶，并采用 XRD和SEM对其进行了表征。以油酸为表面活性剂对纳米镍晶进行表面修饰，以提高其油溶性及分散性；利用四球摩擦试验机 对添加了改性纳米镍晶的基础油的摩擦学性能进行了摩擦磨损实验，并利用金相显微镜对经过摩擦实验的钢球表面进行形貌分 析。实验结果表明，添加了改性纳米镍晶的基础油的减磨和抗磨性能有很大的提高，改性纳米镍晶可在较短的时间内降低油品的 摩擦系数，当改性纳米镍晶的质量分数为1．5％时，油品的摩擦学性能最好。 [关键词]纳米镍晶； 一环糊精；水合肼；摩擦学性能；基础油 [文章编号]1000—8144(2011)06—0614—04 [中图分类号]TQ 138．1 [文献标识码]A Preparation and Tribological Properties of Nickel Nanocrystals as Additives in Base 0il Qian Jianhua，Yin Xiangyu，Xu Jiasheng (Liaoning Provincial Key Laboratory for Functional Compounds Synthesis and Application Bohai University，Jinzhou Liaoning 121003，China) [Abstract]Ni nanocrystals with spongy morphology were prepared by using Ni(C5 H7 O2)2·2H2 O as the precursor，hydrazine hydrate as the reductant and 一cyclodextrin reagent as the modifier．The prepared Ni nanoparticles were characterized by means of XRD and SEM．Oleic acid as the surfactant modified the surface of the prepared Ni nanocrystals．The effect of the modified Ni nanoparticles as additives on the tribological properties of base oil were investigated using a four—ball friction and wear tester，and the surface micrograph for the wear scar of the experimental ball was analyzed by means of metalloscope．As the result sho