金属有机骨架材料MOF_5上噻吩硫化物的吸附分离.pdfVIP

38 5 Vo.l 38No. 5 2010 10 Journal of FuelChem istry and Technology Oct. 2010 : 2010) MOF5 1 2 1 1 1 1 代 伟 , 庄海堂 , 卢信清, 陈 晓, 韩敏敏 ,郑 宇 ( 1. , 321004; 2. , 321004) : OF5, XRDN 2 SE , OF5 , OF5; 0. 90% 1. 92%, 0. 64% 1. 72% , , : ; OF5; ; ; : X511 : A Adsorptive separation of thiophene derivatives viam etal organic fram ework m aterialMOF5 1 1 1 1 1 DAIW ei, ZHUANG Haitang, LU Xinqing, HAN inmin , ZHENG Yu ( 1. College of Chem istry and Lfi e Sciences, J inhua 321004, China; 2. Institute of Phy sical Chem istry, Zhej iang N ormal Uni ersity, J inhua 321004, China) Abstract: A novelmethod for thedeep desulphurization of fuelproductswas investigatedby using themetalorganic framework material OF5 as an adsorben.t OF5 was synthesized hydrothermally and its structure was characterized bymeans ofXRD, SE andN adsorption. The desulphurization performanceof OF5wastested in 2 terms of breakthrough curvesw ith the smi ulated oils at room temperature. The results showed that the adsorbent OF5 possesses quite large sulfur capacity, even larger than those reported previously in literature. The adsorbent breakthrough capacity and saturation capacity for sulfur componentwere 0. 90% and 1. 92% in the aliphatic oi,l and 0. 64% and 1. 72% in the aromatic oil, respectively. The negative effect ofmoisture on the desulphurization performancewas elmi inated by packing itw ith the activated carbon adsorbent together, which provides a new way for thedevelopment of the adsorptive desulphurization pr