3 金属材料合成3-2 B.pdf

Chapter 3-2: Synthesis of metal nanoparticles and films • 3.2.1 Introduction • 3.2.2 Theory: nucleation-seed-nanocrystals • 3.2.3 Chemical reduction method: (synthesis of Au and bi-metallic nanoparticles) • 3.2.4 Sonochemical • 3.2.5 Hydrothermal • 3.2.6 Electrochemical reduction • 3.2.7 Thermolysis and Photolysis • 3.2.8 Chemical Vapor Deposition • 3.2.9 Physical Vapor Deposition (Vacuum evaporation) Keyword : Reduction Examples of metal particles from chemical reduction in aqueous solutions CTAB = cetyltrimethylammonium bromide (C H )(CH ) NBr 16 31 3 3 SDS = sodium dodecyl sulfate CH (CH ) OSO Na 3 2 11 3 Examples of metal particles from chemical reduction in non-aqueous solutions HDA Ex. Preparation of Au nanoparticles by a Ex. Preparation of Au nanoparticles by a chemical reduction route chemical reduction route Reducing agent Capping agent Au3+ Salt Au nanoparticles Parameters Affecting Particle Growth/ Shape/ Structure Parameters Affecting Particle Growth/ Shape/ Structure Type of capping agent/stabilizers: e.g. CTAB Concentration of the reactants CTAB = cetyltrimethylammonium bromide pH value of the solution (C H )(CH ) NBr 16 31 3 3 SDS = sodium dodecyl sulfate Duration of heat treatment CH (CH ) OSO Na 3