CeO2-ZrO2催化CO低温氧化活性的影响.pdfVIP

物理化学学报(WuliHuaxueXuebao) 3278 ActaPhys．一Chim．Sin．，2010，26(12)：3278—3284 Decernber [Article] www．whxb．pku．edu．cn 制备方法对CuOICeO2|ZrO2催化CO低温氧化活性的影响 杨志强 毛东森 郭强胜 顾 蕾 (上海应用技术学院化学与环境工程学院，上海 200235) 摘要： 采用微波加热分解法(一步法)和微波加热处理共沉淀+浸渍法(两步法)制备了CuOC／eOz—ZrO2催化剂， 并对其进行了X射线衍射、低温氮气吸附／脱附和程序升温还原等表征，采用色谱流动法考察了催化剂的催化 CO低温氧化性能．结果表明，一步法比两步法更有利于使催化剂表面CuO高度分散，CuO与CeO-ZrO 间的 相互作用更强，CuO更容易被还原，从而具有更高的催化CO氧化活性．与CeO-ZrO。有相互作用的高分散和 小颗粒CuO有利于催化剂活性的提高，与CeO一ZrO无相互作用的大颗粒CuO对催化剂的活性有抑制作用． 关键词： 催化活性：CuO／CeO一ZrO：CO氧化；微波加热 中图分类号： 0643 EffectofPreparationMethodontheActivityofCuO／CeO2-ZrO2Catalysts forLow TemperatureCO Oxidation YANG Zhi—Qiang MAODong—Sen GUO Qiang—Sheng GULei (SchoolofChemicalandEnvironmentalEngineering,ShanghaiInstituteofTechnology,Shanghai200235，PR．China) Abstract： CuO／CeO2一ZrO2catalystswerepreparedbymicrowave heatingdecomposition (one—step approach)andbymicrowaveheatingtreatmentofCO—precipitationfoIlowedbyimpregnation(two—step approach)．ThecatalystswerecharacterizedbyX-raydiffraction(XRD)，IOWtemperatureN2adsorption／ desorption，andH2．temperature．programmedreduction(H2-TPR)．Thecatalyticactivitiesofthecatalysts f0rIOW temperatureCO oxidationwereinvestigatedusingamicroreactor-gaschromatograph．Theresults showed thatthe one．step approach was more beneficialto CuO dispersion on the catalystsurface becauseofa strong interactionbewt een CuO andCeO2一ZrO2and to the improvedreducibility ofCuO， which resulted In highercatalyticactivity．We conclude thatfinely dispersed and smalICuO particles stronglyinteractwithCeO2，ZrO2areresponsibleforthehighcatalyticactivitytowardCO oxidationandthat