溶胶-凝胶法制备NixCo（1-x）CoAlO4尖晶石型复合氧化物及其催化分解N2O性能.pdfVIP

第43卷 第 1期 燃 料 化 学 学 报 Vo1．43No．1 2015年 1月 JournalofFuelChemistryandTechnology Jan．2015 文章编号：0253—2409(2015)O1-0081-07 CatalyticdecompositionofN2O over NiCo1 CoAIO4spineloxidespreparedbysol-gelmethod 一 x ZHANGHai-jie，WANGJian，XUXiu-feng (InstituteofAppliedCatalysis，YantaiUniversity，Yantai264005，China) Abstract：NiCoh CoA104spineloxideswithdifferentcompositionswereprepared bysol—ge】methodnadfurthermodifiedwiht l(2CO3byincipientimpregnation．TheNiCo CoAIO4spineloxideswerechraacterizedbymenasofnitrogenphysisorption，X’ray diffraction(XRD)，scanningelectronmicroscopy(SEM)，nadtemperature—programmedreductionbyhydrogen(H2一TaR)；hte effectofpreparationpraameterssuch ascomposition，motherliquidpH value，nadpotassium loadingonhteircatalyticactivity in N20 decompositionwasinvestigated．Theresultsshow htathteK／Ni0I5Coo85CoA104catalystprepraedwiht apH valueof3nada K／(Ni+Co)molraratioof0．1ismostactiveforN2Odecomposition；overit，N20cna becompletelydecomposedintonitrogen nadoxygenat450oC inhtepresenceofoxygen ． K-modifiedcatalystsexhibithighcatalyticactiviyt，goodreducibilityandresistance towradswater，asK speciesmaybeabletoweakenhtesurfacemetal—oxygenbonds． Keywords：N20 decomposition；NiCo1一 CoA104；sol—gelmehtod；spineloxide；K modification CLC number：O643 Documentcode：A Asoneofthemostimportantgreen—housegases expansion，in htiswork，we intended to investigate limitedbytheKyotoprotocol，N2O hasahigh global