不同钨基催化剂上葡萄糖和纤维二糖催化转化制备乙二醇.pdfVIP

第 4 4 卷 第 7 期 燃 料 化 学 学 报 Vol. 44 No. 7 2 0 16 年 7 月 Journal of Fuel Chemistry and Technology Jul. 2016 文章编号：0253-2409(2016)07鄄0845鄄08 Catalytic conversion of glucose and cellobiose into ethylene glycol over various tungsten-based catalyst CAO Yue-ling1’2, WANG Jun-wei1’* *, KANG Mao-qing1, ZHU Yu-lei1 (1. Institute o f Coal Chemistry , Chinese Academy o f Sciences ’ Taiyuan 030001’ C hina ； 2. University o f Chinese Academy o f Sciences ’ Beijing 100049’ C hina) Abstract ：Glucose and cellobiose were used as model compounds to investigate the effect of retro-aldol condensation and hydrogenation rates on the product distribution of cellulose conversion. It was shown that the product distribution obtained over the physical mixture of Ni/SBA-15 and W O 3/SBA - 1 5 in the glucose and cellobiose conversions were different from that attained on the Ni-W 〇3/SBA-15 prepared by the co-impregnation method. The ethylene glycol (EG) yield depended on the structures of tungstic compounds’ and it increased in the order of W 〇3 W O 3/SBA - 1 5 ( N H 4 )6W 7 〇2 4 ,6 H 2 〇 ( A M T )’ while the particle sizes of them decreased in such an order. Regardless of the types of tungstic compounds’ the E G yield obtained in the glucose conversion is lower than that attained in the cellobiose conversion at the same amount of catalyst. Key words glucose ： cellobiose ； hydrogenolysis ； tungsten-based catalysts ； ethylene glycol ； CLC num ber : O643 Document co d e : A Lignocelluloses ’ one of the major clean energy