分散聚合制备二氧化硅_聚苯乙烯单分散复合微球.pdfVIP

22 2 4 2005 Acta Materiae Compositae Sinica Vol1 22 No1 2 April 2005 : 1000-3851( 2005) 02-002 1-06 / 李永超, 张 毅, 金日光* ( , 100029) : / / / , SEM T EM : / , PVP K-30 , , L , 11 25 m, E 01 035, , PVP K-30 , , : ; ; ; ; ; : T B 332; T Q 3161 3314 : A SILICON DIOXIDE/ POLYSTYRENE MONODISPERSE COMPOSITE MICROSPHERE BY DISPERSION POLYMERIZATION * LI Yon chao , ZHA NG Yi , JIN Ri uan ( Colle e of Materials Science and En ineerin , Beijin University of Chem ical T echnolo y , Beijin 100029, China) Abstract T he silicon diox ide( SiO ) / poly st yrene( PS) composite microspheres w ere prepared by dispersion poly- 2 merization in ethanol/ water medium. The process of dispersion polymerizat ion was investi ated, and the kinet ics of dispersion polymersion w ith nano-SiO in the reaction system w as studied. The samples w ere characterized by mi- 2 croscopy techniques( SEM , T EM) . It is show n that nano-SiO particles are encapsulated by PS after dispersion poly- 2 merization in et hanol/ w ater medium usin polyvinylpyrrolidone( PVP K-30) as stabilizer. The avera e size of the composite microsphere is 11 25Lm and the dispersion coefficient Eis 01 035. The effects of stabilizer concentration on the size of the microspheres w ere studied. Keywords dispersion polymerization; silicon dioxide; poly st yrene; com posite microsphere; monodisperse;