考试点专业课：2013南京航空航天大学813无机化学考研真题.pdfVIP

考试点考研网     :  :    :        20 0.5 1. 2N O (g) 4NO (g)+ O (g)∆ H 0_____ 2 5 2 2 r m _____________ 2. Cr O 2- + 14H+ + 6e = 2Cr3+ + 7H O 2 7 2 Cr2O72- 3. [CoCl (en) ]Cl ________ ________ 2 2 ______________________ 4. [Cr(NH ) ]3+ 3.9 B.M. ______ 3 6 _________ 5. ______________ 6. Mn 0.56 − + V 2− 2+.27 V 0+.96 V 3+ 1+.50 V 2+ 1−.18 V MnO ⎯⎯⎯→MnO ⎯⎯⎯→MnO ⎯⎯⎯→Mn ⎯⎯⎯→Mn ⎯⎯⎯→Mn 4 4 2 7. H O 2 2 8. 9. AgNO K CrO 3 2 4 KBr Na S O 2 2 3 10. ________________________ ________________ 11. A(g)→B(g)+D(g)400 20%900 t1/2 9 ________ kJ·mol-1 12. 25oC NH HS(s)=NH (g)+H S(g)2.00mol NH HS(s)∆U ∆H 4 3 2 4 _______ 13. HAc HAc 0.050HAc