09 含硫含铝易切钢的可浇性研究.pdfVIP

第十四届全国炼钢学术会议文集 含硫含铝易切钢的可浇性研究 1) 2) 郭银涛 何生平 王谦 杨锋功 杨华峰 董大西 1) 重庆大学材料科学与工程学院, 重庆 400044; 2) 石家庄钢铁有限责任公司，石家庄 050000 摘 要: 水口结瘤是含硫含铝易切钢连铸生产厂中容易出现的事故，对生产顺行和铸坯质量有重大危害。结瘤物主要为 MgO·Al O 、高熔点铝酸钙和CaS 。文章对水口温度以上的非金属夹杂物析出进行了热力学讨论，研究了结瘤物产生原因和 2 3 影响因素。研究发现，钢水中残留的 Al O 促进了尖晶石和高熔点铝酸钙夹杂物的形成，特别是 VD 真空处理导致耐材中 2 3 MgO 及渣中CaO 的分解，产生的Mg 与钢水中的Al O 夹杂促进了铝镁尖晶石的形成；钢-渣脱硫反应是水口堵塞物中CaS 2 3 的主要来源。 关键词：含硫含铝钢；水口结瘤；热力学；精炼渣；可浇性 Study on Castability of Aluminum and Sulphur Bearing Free-cutting steel Guo Yin-tao He Sheng-ping Wang Qian1) Yang Feng-gong Yang Hua-feng Dong Da-xi2) 1) College of Materials Science and Engineering, Chongqing University, Chongqing 400044, China; 2) Shijiazhuang Iron Steel Co., LTD, Shijiazhuang 050000, China Abstract: Nozzle blockage is one of the main problem during continuous casting of Al and S-containing steel, which have a negative effect on smooth producing and product quality. The blockage mainly consisted of MgO·Al O spinel，high-melting-point calcium 2 3 aluminate and CaS. For improving castability, in this study, discussion on precipitation of non-metallic inclusions above nozzle temperature by thermodynamics was carried out. It was found that residual Al O in steel is a significant promoter of MgO·Al O 2 3 2 3 formation, and that CaS mainly results from steel-slag desulfurisation during soft blowing stage. Key words: Al and S-containing steel; nozzle cl