Fe_OH_3改性PVDF膜的制备与其抗污染性能_邱恒.pdfVIP

2009 4 　　　 Vo.l15　No.4 Fe(OH) PVDF 3 邱　恒 (, 　201620 ) 　:通过过滤涂膜的方法把氢氧化铁(Fe(OH))胶体涂在聚偏氟乙烯 (PVDF)膜表面进行膜 3 的表面改性, 研究 制膜压力、Fe(OH)胶体浓度对改性膜性能的影响。在制膜压力 0.15 MP,a 3 2 Fe(OH)胶体质量分数 0.05%的条件下, 制得的改性膜纯水通量为 350 mL/(cm·h)左右, 截留 3 率超过 99%,高于未改性膜。在膜生物反应器 (MBR)中,改性膜的出水水质优于未改性膜。污染 膜清洗后,改性膜纯水通量恢复率高出未改性膜 12%;通过扫描电镜 (SEM)分析亦表明, 改性 PVDF膜抗污染性能提高。 :氢氧化铁胶体　聚偏氟乙烯膜　表面改性　抗污染性 :TQ028.8 X703　　:A　　:1674 -0254 (2009 )04-000 1-05 PreparationforPolyvinylideneFluorideMembraneModified byFerricHydroxideanditsAnt-ipollutionPerformance QIUHeng (CollegeofEnvironmentalScience Engineering, DonghuaUniversit,yShanghai20 1620, China) Abstrac:tInthepape,rpolyvinylidenefluoridemembranesurfaceiscoatedwithferrichydroxide colloidtomodifythemembranesurfaceperformancebyfilteringmethod.Theeffectsofpressurewhile producingmembraneandconcentrationofferrichydroxidecolloiduponmodifiedmembranewerein- vestigated.Whenthepressureofmembranepreparationwas0.15 MPaandthemassfractionsoffer- 2 richydroxidewas0.05%, themembranepurewaterfluxwasabout350 mL/(cm·h)withrejectionrate above99%, higherthanunmodifiedmembrane.Thequalityofeffluenttreatedbymodifiedmembranewasbetter thanunmodifiedmembraneinmembranebio-reacto.rAftercleared, thepurewaterfluxrecoveryratioofpollu- tedmodifiedmembranewas12% higherthanunmodifiedmembrane.Andtheanalyseofscanningelectronmi- croscopy(SEM)alsoindicatedthattheant-ipollutionperformanceofmodifiedPVDFmembranemipro