HDPE-AA-SSS预辐照接枝膜的表征及其湿敏性能的研究.pdfVIP

高校化学工程学报 NO.3 Vo1.21 第 21 卷第3 期 2007 年 6 月 Jouma1 ofChemical Engineering ofChinese Universities June 2007 文章编号: 1003-9015(2007)03-0500-05 HDPE-AA-SSS 预辐照接枝膜的表征及其湿敏性能的研究 李珍，吴明红，焦正，姐建华，王德、庆，顾建忠 (上海大学环境与化学工程学院射线所， 上海201800) 摘 要:采用预辐照法将亲水性单体丙烯酸(AA)和对苯乙烯磺酸纳(SSS)接枝到疏水性高密度聚乙烯(HDPE)薄膜上， 制备出新型的接枝膜湿敏元件.通过扫描电镜观测了辐照接枝前和接枝后 HDPE 膜的表面形貌，并通过红外光谱表征 了膜的结构，同时测定了接枝膜湿敏元件的湿敏性能.实验结果表明，制备的接枝膜湿敏元件具有良好的湿敏特性， 响应和恢复时间短.它具有较好的稳定性，能在高湿、高温环境下使用。实验结果也表明了接枝HDPE 膜具有良好的 湿敏性能。 关键询:预辐照法， HDPE-AA-SSS，接枝膜湿敏元件:表征:湿敏性能 中圈分类号: TP212.2 , TQ325.12 , TQ316.343 文献标识码:A Characteristic and Humidi句ty Sensing Prope时ies of HDPE-AA-SSS Grafted Films Prepared by Preirradiation Method LI Zhen, WU Ming-hong, JIAO Zheng , ZU Jian-hua, WANG De-qi吨， GU Jian-zhong (School ofEnvironmental and Chemical Engineering, Applied Radiation Institute , Shanghai University, Shanghai 201800 , China) Abstract: A new kind of humidity sensitive film w臼 prepared by grafting hydrophilic sodium styrene sulfonate (SSS) and ac叩lic acid (AA) onto hydrophobic high-density polyethylene (HDPE) film via preirradiation method. The structure and surface mo叩hology ofbo伽 grafted and ungrafted HDPE films were observed by FTIR spectroscopy and scanning electron micros∞pe (SEM) , respectively. The humidity sensing properties of the humidity sensors prepared by using the grafted films were investigated. The experimental results show that the humidity sensors with grafted film exhibit excellent humidity sensing properties , their response and recove可 processes are fast, and their thermal stability 缸e good too. Therefore they can be used under high humidity and high temperature co