PMMA-PAN核壳结构复合乳胶的制备与表征.pdfVIP

功能高分子学报 Vo l. 28 No. 1 52 ]ournal of Functional Polymers 2015 年 3 月 PMMA-PAN 核壳结构复合乳胶的制备与表征 张武警， 何艳， 张幼维， 赵炯心 (东华大学材料科学与工程学院，纤维材料改性国家重点实验室，上海 201620) 摘 要: 采用疏水引发剂引发的半连续元皂乳液聚合法，合成了 Z 均流体力学直径约 70 nm 的 聚甲基丙烯酸甲醋(PMMA) 纳米乳胶。以 PMMA 纳米乳胶为种子，采用疏水引发剂引发的种子 乳液聚合法，制备了 PMMA 聚丙烯腊(PAN)核壳结构复合乳胶。采用动态光散射、傅里叶红外光 谱、扫描电镜和透射电镜表征了各种乳胶粒的组成、尺寸、结构和微观形态。研究了反应温度、羊体 用量和表面活性剂用量对 PMMA-PAN 复合乳胶粒的结构和形态的影响。结果表明 :PMMA­ PAN 复合乳胶粒为核壳结构，其壳层厚度可通过改变羊体用量进行调整。 关键词: 种子乳液聚合;聚丙烯腊;聚甲基丙烯酸甲西旨;核壳结构 中国分类号: TQ316. 33+ 4 文献标志码: A 文章编号: 1008-9357(2015)01-0052-05 Preparation and Characterization of PMMA-PAN Core-Shell Composite Latex Particles ZHANG Wu-jing , HE Yan , ZHANG You-wei , ZHAO Jiong-xin (State Key Laboratory for Modification of Chemical Fibers and Polymer Materials , College of Materials Scienc巳 and Engineering , Donghua University , Shanghai 201620 , China) Abstract: Poly(methyl methacrylate) (PMMA) nano-latex with a Z-av巳rage hydrodynamic diameter of approximately 70 nm was synth巳sized by hydrophobic initiator-initiated semi-continuous soapless emulsion polymerization. PMMA-polyacrylonitrile (PAN) core-shell composite latexes were prepared via hydrophobic initiator-initiated seeded emulsion polymerization using PMMA nano-latex as the se巳ds. Dy- namic light scattering , Fourier transform infrared spectroscopy , scanning electron microscopy and trans- mlsslon 巳lectron microscopy w巳re used to characterize th巳 size ， composition , structure and morphology of various latex particles. The influenc巳s of the reaction temperature , the amounts of acrylonitrile and surf