Cu-Zr二元系非晶合金的玻璃形成能力预测.pdfVIP

理化学学报(Wuli Huaxue Xuebao) June Acta Phys. Chim. Sin., 2007, 23(6) ：895-899 895 [Article] Cu Zr 二元系非晶合金的玻璃形成能力预测 丽1 惠希东1,2, 陈国良1 LIU Zi Kui2 1 2 ( 北京科技大学, 新金属材料国家重点实验室, 北京 100083; Department of Materials Science and Engineering, Pennsylvania State University, University Park, PA 16802, USA) 摘要： 按照无序固溶模型和线性化合 自由能模型, 对Cu Zr 二元系合金过冷熔体的结晶驱动力采用Turnbull 和Thompson Spaepen (TS) 两种近似公式进行了计算. 以连续形核理论为基础, 利用Davies Uhlmann公式计算了八 种成分合金的两组温度-时间转变(TTT) 曲线和临界冷却速度. 计算结果表明, 关于玻璃形成能力的两组计算值 与实验值都比较吻合, 利用TS 公式计算得到的临界冷却速率更接近实验值, 说明该方法能更好地预测Cu Zr 二 元体系的玻璃形成能力. 关键词： Cu Zr 二元系; 玻璃形成能力; 温度-时间转变曲线; 临界冷却速率 中图分类号： O643 Prediction of the Glass Forming Ability of Cu Zr Binary Alloys GE Li1 HUI Xi Dong1,2, CHEN Guo Liang1 LIU Zi Kui2 1 ( State Key Laboratory f or Advanced Metals and Materials, University of Science and Technology Beij ing, Beijing 100083, P. R. China; 2Department of Materials Science and Engineering, Pennsylvania State University, University Park, PA 16802, USA) Abstract ： Based on the random solution model and stoichiometric intermetallic compound Gibbs free energy model, the driving forces for the crystallization from the undercooled liquid of Cu Zr binary alloys were evaluated by using Turnbull and Thompson Spaepen (TS) approximate equations, respectively . Using Davies Uhlmann kinetic formulations within the frame of continuo