燃煤烟气中汞的脱除大学论文.doc

摘 要 煤炭作为我国的主要能源这一现状在很长时间内难以改变，大量的煤炭消耗带来了严重的环境问题，从而引起越来越多人的关注。我国是世界上汞排放量最大的国家之一，因此必须对其进行控制。汞因为具有挥发性、持久性和生物积累性，难以脱除。传统的活性炭吸附剂价格昂贵，不能再生利，无法达到理想的工业脱汞效果。Abstract Coal is still and will be the mainly energy source in a long time for China. Huge amount of coal consumption will result in serious environmental problem， this cause more and more peoples attention. China is one of the largest mercury emissions countries in the word. Therefore the mercury emissions control is reasonable and necessary. Mercury is difficult to remove because of its volatile ， persistence， and biological gatz. Traditional activated carbon adsorbent is expensive， not renewable use，and can not reach the ideal effect of industry to take off the mercury. In this paper， natural mineral materials were applied as alternative to activated carbons due to their low cost. The main research is about mercury removal performance of attapulgite (Atp) and modified attapulgite in coal-fired flue gas. In the experiment, Attapulgite is modified by KMnO4 or NH4Br.They are impregnated, calcited and filtered out 60 to 100 meshes as adsorbent. The mercury removal adsorbent effects of adsorbent were tested by QM201H flue gas mercury analyzer in a fixed bed on the condition of a simulated flue gas (N2, mercury vapor). The mercury removal mechanism of modified attapulgite was analyzed in a brief. Through the method of controlling the variable, This experiment studied the modifier concentration, adsorbent temperature, modified reagent for mercury removal efficiency. The curve of mercury removal efficiency was drawed. The characterization of modified attapulgite samples was tested by SSA-4300 surface area analyzer. Combining with it, analysis and discussion is necessary for the verity of mercury removal efficiency. The results showed that, after modification by KMnO4, mercury removal efficiency of the attapulgite has greatly improved, with increasing temperature, it increased slightly and can reach an average of about 7