影响DSC剖析结果的主要成分（国外英文资料）.docVIP

影响DSC分析结果的主要因素（国外英文资料） The main factors influencing the analysis of DSC 1. The sample weight Sample size is low, the sample is high in resolution, but the sensitivity is decreased, and the sample size is generally adjusted according to the sample heat effect size, usually 3 ~ 5mg. On the other hand, the temperature of the change of sample was also affected. With the increase of sample weight, the initial peak temperature basically remain unchanged, but the peak temperature increases, the peak end temperature is increased, so as the similar samples to compare the difference, had better use the same amount. Rate of warming The temperature range is usually 5 ~ 20 degrees/min. Generally speaking, the faster the temperature increases, the sensitivity increases and the resolution decreases. Sensitivity and resolution are a pair of contradictions, and people generally choose slower rate of warming to maintain good resolution and to increase the sample size to improve sensitivity. In general, as the rate of temperature increase increases, the temperature change of the melting peak is not small, and the peak and peak end the temperature increase, and the peak becomes wider. 3. The atmosphere General use of inert gas, such as nitrogen, argon, helium, etc., wont produce oxidation peak, at the same time can reduce the sample volatiles to monitor the corrosion. The flow velocity must be constant (eg, 10ml/min), or it will cause a baseline fluctuation. The nature of gases has a significant effect on measurement, which should be noticed. Such as helium gas thermal conductivity than that of nitrogen and argon gas thermal conductivity is about 4 times, so doing the DSC using helium as shielding gas of low temperature and cooling speed, shorten test time, but because the helium gas thermal conductivity high, lower the peak detection sensitivity, is about 40% of the nitrogen, therefore, when the heat is measured in the helium to use standard material to calibrate first for approval.