钠离子电池电解液文献.pdfVIP

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钠离子电池电解液文献.pdf

View Online / Journal Homepage / Table of Contents for this issue Dynamic Article Links Energy C Environmental Science Cite this: Energy Environ. Sci., 2012, 5, 8572 /ees PAPER In search of an optimized electrolyte for Na-ion batteries Alexandre Ponrouch, *ac Elena Marchante,ac Matthieu Courty,bc Jean-Marie Tarasconbc *ac and M. Rosa Palacın Received 17th May 2012, Accepted 12th June 2012 DOI: 10.1039/c2ee22258b 2 B 1 8 0 5 2 2 r 2 Electrolytes are essential for the proper functioning of any battery technology and the emerging Na-ion e 2 b E technology is no exception. Hence, a major focus on battery research is to identify the most appropriate m E e 2 t C formulation so as to minimize interface reactions and enhance both cell performances and safety p e / 9 S 3 aspects. In order to identify suitable electrolyte formulations for Na-ion chemistry we benchmarked 7 0 0 1 . n 0 various electrolytes containing diverse solvent mixtures (cyclic, acyclic carbonates, glymes) and Na- o 1 : S i o based salts having either F-based or perchlorate anions and measured viscosity, ionic conductivity, and A d | C , g thermal and electrochemical stability. The binary EC:PC solvent mixture has emerged as the best s r c o i c. solvent formulation and has been used to test the performance of Na/hard carbon cells with b

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