镍氢电池自放电行为研究_王仲民.pdfVIP

26 3 Vol. 26, No . 3 2006 6 Journal of Gui lin University of El ectron ic Technology Jun. 2006 a 王仲民, 姚青荣 ( 桂林电子科技大学 信息材料科学与工程系, 广西 桂林　541004) : ( Ni-MH) ( G) , , : , , : ; ; ; : T G 139: A : 1001-7437( 2006) 03-0203-04 Study of self -discharge behavior of Ni -MH batteries - , - WA N G Zhong m in YA O Qing r ong ( De t. of M aterial Science and Engineering, Guilin University of Electronic T echnology , Guilin 54 1004, China) : - ( ) Abstract Charged Ni MH batteries are in a state of high Gibbs energy G in relat ion t o that of their discharged states. As a result , there is a therm odynamic driving force for t heir self-discharge on o en-circuit. Several mechanisms for self-discharge, rinci les of self-discharge, like electrode reactions, kinet ics, redox shuttles, , . - charge retent ion are out lined and analyzed in this a er Self discharge is determ ined by the mechanism and rates , of rocesses that can t ake lace at the interfaces of the electrodes of the device as influenced by the kinetics of the elect rochemical rocesses involved. For its im ortant a lication of Ni-MH battery and the redicat ion of battery erformance, it is w orthy of doing further ex eriment al investigat ion into it and make it realist ic t o incor orat e the - . self discharge henomenon into battery design and o erat ion : - ; - ;