B位的Fe掺杂对LaMnO3电磁特性的影响.pdfVIP

第 23 卷第1 期 无机材料学报 Vo l. 23 , No. 1 2008 年 1 月 Journal of 1norganic Materials Jan. , 2008 文章编号: 1000-324X(2008)0l-0008-05 B 位的 Fe 掺杂对LaMn03 电磁特性的影响 蔡之让 17 童伟 27 张贝 27 张裕恒 2 (1.宿州学院材料研究室，宿州 234000; 2. 中国科学技术大学结构分析开放实验室，合肥 230026) 摘要z 通过测量样品的 M-T 曲线、 ESR 曲线、 ρ -T 曲线和 MR-T 曲线，研究了 Fe 掺杂 (x=0.05， 0.10, 0.20 , 0.30 , 0.40) 对 LaMn03 磁电性质的影响.实验结果表明s 随掺杂浓度的增加，体系的 Tc 单调下降，所有 3 掺杂样品均有铁磁- )1顶磁 (FM-PM) 相变，但均无金属-绝缘体 (1M) 转变.这些结果归因于 Fe 掺杂引起 Fe + 与 Mn3+之间的双交换作用和 J-T 畸变. 关键词z 庞磁电阻;磁结构:输运行为;J;J..交换 中图分类号: 0482 文献标识码:A Influence of Fe Doping at B Site upon Electric and Magnetic Properties of La岛in03 System 1 2 2 2 CA1 Zhi-Rang , TONG 认Tei ， ZHANG Bei , ZHANG Yu-Heng (1. Materials Research Laboratory, Suzhou College , Suzhou 234000 , China; 2. Structure Research Laboratory, University of Science and Technology of China, Hefei 230026 , China) Abstract: By measuring M - T curves , ESR curves , p - T curves and M R - T curves of the samples , the influences of Fe doping (x=0.05 , 0.10 , 0.20 , 0.30 , 0.40) upon magnetic and electric properties of LaMn03 were studied. The experimental results indicate that all samples undergo the transition from paramagnetism to ferromagnetism at Tc . For the doped samples , there is a paramagnetic-ferromagnetic (PM-FM) transition but there is no insulator-metal(IM) transition. The results are attributed to double exchange interaction between Fe3+ ions and Mn3+ ions and Jahn-Teller effects. Key word