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泥土情况化学问答题(国外英文资料)
土壤环境化学问答题(国外英文资料)
Soil environmental chemistry focuses on problem sets and reference answers
What is the active acidity and latent acidity of the soil? Try their relationship to discuss the reasons for the high acidity of the soil in the south of China.
According to the presence of H + in soil, the acidity of soil can be divided into two categories: active acidity and latent acidity.
(1) active acidity: the active acidity of the soil is a direct reflection of the concentration of hydrogen ions in the soil solution, also known as the effective acidity, usually in pH.
(2) latent acidity: the origin of soil latent acidity is the exchangeable H + and Al3 + of soil colloid adsorption. When these ions in adsorption state, doesnt is acidic, but when they after ion exchange action into the soil solution, can increase the soil solution of H + concentration, lower the soil pH value.
Southern rock or soil in the soil parent material of lattice by different degree of damage, which results in the lattice of Al3 + released, become exchangeable Al3 +, increased the latent soil acidity, under certain conditions into active soil acidity, show the pH value decreases, and acidity on the high side.
What are the buffer effects of soil? Give an example of how it works.
Soil buffer performance includes the buffer performance of soil solution and the cushioning properties of soil colloid:
(1) the cushioning properties of soil solution: the weak acid and its salts such as H2CO3, H3PO4, H4SiO4, humic acid and other organic acids in soil solution are cushioned. Take the example of carbonic acid and sodium salt. Adding hydrochloric acid to the soil, sodium carbonate and its production of neutral salt and carbonic acid, greatly inhibit the improvement of soil acidity.
Na2CO3 + 2HCl2NaCl + H2CO3
When the Ca (OH) 2 is added, carbonic acid is used to produce calcium carbonate, which also limits the range of soil alkalinity.
H2CO3 + Ca (OH) 2CaCO3 + 2H2O
Soil of some organic acid (such as amino ac
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