利用D309树脂离子交换分离宏量钨和钼.pdfVIP

Availableonlineat、lI，1sciencedirect．COITI Transaetionsof 繇 ScienceDirect NonferrousM etals SocietyofChina ELl ER Press Trans．NonferrousMet．Soc．China24(2014、3008—3013 www ．tnm sc．cn Separationofmacroamountsoftungstenand molybdenum byionexchangewithD309resin Xiao-yingLU，Guang—shengHUO，Chun—huaLIAO SchoolofMetallurgyandEnvironment，CentralSouthUniversity,Changsha410083，China Received25May2014；accepted2September2014 Abstract：Basedonthedifferenceintendencytopolymerizebe eentungstenandmolybdenum．anew methodusingD309resin waspropounded．Thebatchtestsindicatethattheoptimum pH valueandcontacttimefortheseparationare7．0and4hrespectively, themaxium separation factorofW andMois9．29．And theexperimentalresulesshow thatisothermalabsorbingtungstenand molybdenum belongstoLangmuirmodelandFreundlichmodelrespectively,andtheabsorbingkineticsofrtungsteniscontrolledby intra．particlediflusion．Withasolutioncontaining70geLWO and28．97gL／Mo，theeffiHentwithamassratioofMotoW0 of76 andtheeluatewithamassratioofWO1tOMoof53．33areobtainedaftercolumntest． Kevwords：highconcentratedtungstateandmolybdenum solution；ionexchange；batchtests：columntests Exceptofrthedifferentaffinitiesofutngsten and 1IntrOductiOn molybdenum towardssulfur．thedifierenttendenciesto