改性X分子筛甲醇／甲苯共吸附原位红外表征.pdfVIP

学兔兔 石 油 化 lT · 64· PETROCHEMICAL TECHN0L0GY 2016年第45卷第1期 DOI：10．3969~．issn．1000—8144．2016．01．011 改性X分子筛甲醇／甲 苯共吸附原位红外表征 张荆清，王建强，蒋 见，袁志庆，许中强 (中国石化 上海石油化工研究院，上海 201208) [摘要]采用原位红外光谱法表征了负载一定量KOH和H BO 的x分子筛催化剂，分析了不同改性分子筛上甲醇／甲苯吸附的原 位红外特征峰，考察了KOH浓度和不同H，BO，负载量对改性的x分子筛甲醇／甲苯共吸附的影响，并研究了原位红外光谱定量 分析结果与催化剂性能的关联性。实验结果表明，采用甲醇吸附在分子筛上的特征峰(2 824 cm )和甲苯吸附在分子筛上的特 征峰(1 596 cm )的峰面积和峰面积比值可有效定量x分子筛酸碱性对甲醇／甲苯的吸附能力的影响；原位红外光谱表征结果可 与催化剂性能相关联，为开发高性能甲醇／甲苯侧链烷基化反应的催化剂提供了一种重要的研究途径。 [关键词]原位红外光谱；X分子筛；甲醇；甲苯；共吸附；侧链烷基化反应 [文章编号]1000—8144(2016)01—0064—05 [中图分类号]TQ 203．2 [文献标志码]A Characterization of coadsorption of methanol and toluene on modified X zeolite by in situ FTIR ZhangJingqing，WangJianqiang，JiangJian，Yuan Zhiqing，Xu Zhongqiang (S1NOPEC Shanghai Research Institute ofPetrochemical Technology，Shanghai 201208，China) l Abstract l A series of X zeolite catalysts with KOH and H BO were characterized by means of in situ FTIR and the adsOrpti0n／cOadsOrptiOn Of methanol and／or toluene on the modified X zeolite catalysts were investigated．The influences 0f KOH concentration and H1BO1 loading on the coadsorption of methanol／toluene were studied．The relationship between the quantitative results of the coadsorption and the catalyst performances was researched．It was showed that，the peak areas and the area ratios of the methanol characteristic peak at 2 824 cm。。and the toluene characteristic peak at 1 596 em could be used to quantitatively describe