稀土发光材料剖析.doc

毕业论文（设计） 题 目： 燃烧法制备YAG：Ce3+荧光粉 院 系： 物理学院 专 业： 应用物理 姓 名： 刘谦 指导教师： 徐晓娟 完成日期： 二〇一六年五月 摘 要 稀土发光材料以其长余辉时间、高发光亮度以及无辐射无污染等优异特点，成为了当前国内外研究的热点方向。稀土发光材料包括基质和激活剂两部分组成，其主要合成方法包括高温固相法、溶胶-凝胶法、燃烧法等。燃烧法作为一种新型的合成方法，即便研究时间较短，但是仍然表现出了极高的应用前景。 而白光LED作为一种节能、高效、环保、长寿命的新型固态照明技术，被誉为第四代新型照明光源。有关白光LED方面的探索也将是稀土研究的重要方向。本论文将采用燃烧法制备白光LED的主要原料YAG：Ce3+荧光粉，并探究其最佳的制备条件和制备方案。 本次实验采用低温燃烧法合成YAG：Ce3+光致发光荧光粉,以A1(N03)3·9H20, Y(N03)3·6H20 和 Ce(N03)3·6H20 为氧化剂采用尿素作为还原剂。并用荧光光谱仪对YAG：Ce3+粉体的激发光谱、发射光谱进行测试。实验结果表明： 燃烧温度与激发强度没有线性关系。 Ce3+的掺杂比例并非越高越好，其最佳掺杂比例为0.06。 尿素的加入比例对实验结果有很大的影响，尿素加入量过少将无法成功制备出发光粉体。 一定的燃烧时间有助于粉体性能的增强，随燃烧时间的增加粉体激发强度将逐渐变高。 关键词：YAG荧光粉；燃烧合成；发光材料；稀土 Abstract Rare earth luminescent materials with high brightness, long luminous time and no radiation no pollution and excellent characteristics, has become a hot research direction at home and abroad. Rare earth luminescent material is composed of two parts, the matrix and the activator. The main synthesis methods include high temperature solid state method, sol- gel method, combustion method and so on. As a new synthesis method, combustion method, even though the research time is short, still has a very high application prospect. The white LED as an energy efficient, environmentally friendly, the new long-life solid-state lighting technology, known as the fourth generation of new lighting. The exploration of white LED will be an important direction of rare earth research. In this paper, we will use the combustion method to prepare the YAG:Ce3+ phosphor which is the main raw material of white LED , and explore the best preparation conditions and preparation method . The YAG: Ce3+ was prepared by low-temperature combustion phosphors synthesis method, process with A1(N03)3·9H20, Y(N03)3·6H20 and Ce(N03)3·6H20 as oxidant and urea as reducing agent. The excita