柠檬酸的检测(国外英文资料).docVIP

柠檬酸的检测(国外英文资料) The water used in this test is distilled water or ion-exchange water. 2.1 differential test 2.1.1 reagent and solution 2.1.1.1 sulphuric acid (GB 625); 2.1.1.2 mercury sulfate: according to take 5 g yellow mercuric oxide (HG3-1069), with 40 ml water first, and then slowly add 20 ml of sulphuric acid, and while stirring, add 40 ml, stir to dissolve it; 2.1.1.3 potassium permanganate (GB 643) : 0.1 N solution; 2.1.1.4 hydroxide (GB 629) : 4.3% (W/V) solution; 2.1.1.5 acetic anhydride (GB 677); 2.1.1.6 pyridine (GB 689); Sample solution: 5mg citric acid per milliliter. 2.1.2 test procedure 2.1.2.1 take a small sample and burn it with a straight fire. It will break down slowly, but not the caramel odor. 2.1.2.2 take a sample solution of 2ml, and adjust it to neuter with 4.3% of sodium hydroxide. Add 1 drop of dilute sulphuric acid and heat to boil. Add 1 to 0.1 N, potassium permanganate, shake, and purple fade. Add 1 drop of sulphuric acid mercury solution to produce white precipitate. Take the sample 5mg, and add the pyridine - acetic anhydride (3:1) about 5ml, the solution that produces yellow to red or purple. 2.2 levels 2.2.1 reagent and solution 2.2.1.1 soda standard solution (GB 629) : 1N solution and the preparation and calibration of the preparation of standard solution by GB 601; 2.2.1.2 phenolphthalein (HGB 3039) : 1% (W/V) solution, which is formulated by GB 603 preparation of preparation and product preparation. 2.2.2 test procedure according to take 1.5 g sample (called a quasi to 0.0002 g), add 50 ml neutral distilled water dissolved, add 3 drops 1% phenolphthalein indicating liquid, with 1 n naoh standard solution titration end to pink. 2.2.3 calculation V. x 0.06404 C -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- (1) M (1-0.08566) V. x 0.06404 C X2 = -- -- - * 100......... (2) m Type: X1 - one water citric acid content. X2 - no water citric acid content, %; V - titration sample of sodium hydroxide standard solution volume, ml; The con