内蒙胜利褐煤腐殖酸对煤平衡复吸水的影响.pdfVIP

第44卷 第11期 燃 料 化 学 学 报 Vol.44 No.11 2016年11月 Journal of Fuel Chemistry and Technology Nov. 2016 文章编号:0253-2409(2016)11-1281-06 内蒙胜利褐煤腐殖酸对煤平衡复吸水的影响 * 刘红缨 ,郝国军,朱雨曦,杜倩倩,朱书全 (中国矿业大学(北京) 化学与环境工程学院,北京 100083) 摘 要:研究了褐煤中重要的成分腐殖酸对褐煤水分的影响。 测定了内蒙胜利褐煤中腐殖酸含氧官能团的含量,并分析了褐 煤、棕黑腐殖酸和残余煤的等温吸附和脱附曲线。 通过Dent 吸附等温模型研究了褐煤和棕黑腐殖酸第一层吸附和第二层吸 附。 结果表明,胜利褐煤2/ 5羧基和1/ 5羟基是由腐殖酸提供的。 棕黑腐殖酸相对褐煤孔径和孔容较小,不利于水簇的形成。 腐殖酸对褐煤的复吸水是不利的。 关键词:褐煤;腐殖酸;平衡复吸附水含量;等温吸附 中图分类号:TD984 文献标识码:A Effect of humic acid on equilibrium adsorption of water of Shengli lignite * LIU Hong-ying ,HAO Guo-jun,ZHU Yu-xi,DU Qian-qian,ZHU Shu-quan (School of Chemical and EnvironmentalEngineering,China University of Mining and Technology (Beijing),Beijing 100083,China) Abstract:The effect of humic acid,an important component of lignite,on the water content in Shengli lignite was studied. The content of oxygen containing functional groups of humic acid in Shengli lignite was determined. The isothermal adsorption and desorption curves of the lignite,brown humic acid and the residual coal were analyzed. Further the primary and secondary site adsorption of the lignite,brown humic acid and the residual coal were studied. The results show that2/ 5 carboxyl and 1/ 5 hydroxyl in Shengli lignite are provided by humic acid. The pore size and pore volume of brown humic acid are smaller than those of the lignite. So brown humic acid is unfavorable for the formation of water clusters. The humic acid is adverse to equilibrium adsorption of water for Shengli lignite. Key words:lignite;humic acid;equilibrium adsorption of water;isothermal adsorption [12] [13] 中国褐煤资