TBA-B2SIWnAI固相7热分解动力学.docVIP

TBA- B2SiWnAI固相热解机理及动力学研究 摘要: TBA- B2SiWnAI采用TG-DTG技术研究了标题化合物的热分解机理及非等温动力学,它的热分解过程经历了2个阶段,其中间体和残余物运用TG-DTG技术进行了确证。采用Coats-Redfern方程和Doyle方程对非等温动力学数据进行了分析,得到了表观活化能分别为149. 87，116.04、 the mechanism and dynamics research Abstract: TBA- B2SiWnAI was reported and characterized with elemental analysis, IR spectrum, and TG-DTA. The TG-DTG curves showed that it thermal decomposition was a three-step process. The intermediates and residue of the thermal data decomposition were identified by means of TG-DTG technique. The non-isothermal kineti data were analyzed with theCoats-Redfern and Doyle equation.