分子离子双激发解离通道的竞争研究及激光光电子与中性分子碰撞频率的实验研究.pdfVIP

摘要 发射流冷却的CO分子至B1∑+激发态，用光电倍增管测量了CO分子 B1∑+一A‘n，跃迁产生的激光诱导荧光，由此对该套实验装置进行了初步调试， 得到了较满意的结果。 关键词： 激发截面分支比 非弹性碰撞激光诱导荧光激发谱 II Abstract Abstract Thisdissertationofthree betweentwoexcitation— composesparts：“Competition dissociationchannelsformolecular on collision study Ions”，“Experimental frequenc— iesofelectrons laserwith onlaser- producedby molecules”and‘‘Experimentalstudy inducedfluorescence”．Themaincontentsaresummarizedasfollows． betweentwo for 1．Competitionexcitation—dissociationchannelsmolecularIons Whenthemolecularions excited fioman XYZ+(XY[)aresimultaneously electronicstateintotwo electronicstatesandwith disso· E0 higher Ea EB supervened ciationor betweenthe仅and p predissociation，competition channelsoccurs．Atheoreticalmodelis todealwiththe ofthe provided competition two excitation—dissociationchannelswithmorethantwokindsofionic for products the that the ratesoftwostatesand XYZ+(xY2+)．Supposingphoto·excitation Ea EB aremuchlessthantheirdissociationor theoretical predissociationrates，a equation Canbededucedtofitthemeasured reflectsthe ofthe data，which dependen