Pr3+掺杂GeS2Ga2S3NaCl玻璃的微结构与发光-武汉理工大学学报.PDF

27 7 武 汉 理 工 大 学 学 报 Vol. 27 No. 7 2005 7 JOURNAL OF WUHAN UNIVERSITY OF TECHNOLOGY Jul. 2005 3+ Pr GeSGa SNaCl 2 2 3 刘 盛, 陶海征, 赵修建, 董国平 ( , 430070) : 研究了GeS Ga S NaCl 系统玻璃的热学属性, 并将组成为0. 7GeS 0. 2Ga S 0. 1NaCl 的样品作为最佳的玻 2 2 3 2 2 3 璃基质材料, 进行Pr3+ 离子的掺 , 以制备适用于 1. 3m 光纤放大器的基础材料根据Raman 光谱对玻璃的微观结构 进行了探测通过YAG: N 激光器的泵浦, 观察到了位于1 340 nm 和1 636 nm 的发光峰 : 硫卤玻璃; 微结构; 荧光 : TN 213 : A :2005) Micros ruc ure and Luminescence Proper ies of he 3+ Pr doped GeS Ga S NaCl Glasses 2 2 3 L I U Sheng , T A O H aiz heng , ZH A O X iuj ian , D ON G G uop ing ( Key Laboratory for Silicate Materials Science an Engineering of Ministry of E ucation, Wuhan Universit y of Technology, Wuhan 430070, China) An optimum host glass ( 0. 7GeS 0. 2Ga S 0. 1NaCl) for 1. 3 m optical amplificat ion was investigate within Abs rac : 2 2 3 the GeS Ga S NaCl glasses accor ing to its thermal abilit y. M icrostructural probing w as con ucte accor ing to the Raman 2 2 3 scattering technique. Pr3+ ions were ope into the glass an its emission properties were examine . Un er the excitation of the YAG: N laser, two intense luminescence ban s ( 1 340 nm an 1 636 nm) were observe . Key words: chalcohali e glasses; microstructure; luminescence ( EDFA) 1. 55 m , [ 1] 3+ 1 3 1. 3 m Pr