硫化体系在丁腈手套制备中的应用.pdfVIP

2009 年37 卷第2 期 · · 广州化工 133 硫化体系在丁腈手套制备中的应用 周卫平，邓阳萍 （惠州学院化学工程系，广东 惠州 516015） 摘 要：介绍了N－羟甲基丙烯酰胺（N-AM）硫化体系在丁腈手套制备中的应用。实验采用羧基丁腈胶乳（XNBRL）为 原料，以N-AM为硫化剂、二丁基二硫代氨基甲酸锌（BZ）为促进剂、ZnO为硫化活性剂，经过预硫化、硫化、干燥等过程制得羧 基丁腈胶膜。通过测试胶膜性能，研究了A(N-MA)、B(ZnO)、C（BZ）配比等因素对胶膜物理机械性能的影响，发现C（BZ）是影响 胶膜物理性能的主要因素，其次是A(N-MA)和B(ZnO)。研究最终确定了最佳硫化体系配比A:B:C为3.5:2:1。 关键词：羧基丁腈胶乳(XNBRL)；N-羟甲基丙烯酰胺（N-AM）；二丁基二硫代氨基甲酸锌（BZ）；硫化 Application of N-methylolacrylamide Sulfuration System on the Preparation of Butyronitrile Gloves ZHOU Wei-ping, DENG Yang-ping （Department of Chemistry Engineering, Huizhou University, Guangdong Huizhou 516015, China） Abstract ：The application of N -methylolacrylamide sulfuration system on the preparation of butyronitrile gloves was introduced. Carboxylic acrylonitrile butadiene rubber latex (XNBRL) as raw material, N - methylolacrylamide (N-MA) was used as curing agent, zinc dibutyl dithiocarbamate (BZ) as accelerating agent and ZnO as vulcanizing activator, after the process of pre- sulfuration, sulfuration and desiccation, carboxylated nitrile film could be produced. Through the test, the impact on films mechanical properties could be attributed to different mixture ratio of A (N-MA), B(ZnO), C(BZ). It was found that C(BA) was the major factor to impact films mechanical properties, followed by A(N-MA) and B(ZnO). The best mixture ratio of A(N-MA), B(ZnO), C(BZ) for the curing system was then determined at 3.5:2:1. Key words ：carboxylic acrylonitrile butadiene rubber latex; N-methylolacrylamide; zinc dibutyl dithiocarba- mate; sulfuration ［2~5］ 丁腈胶乳