准东煤碱金属赋存形态及对燃烧特性的影响.pdfVIP

第 20 卷第3 期 燃烧科学与技术 Vo 1.20 NO.3 2014 年6 月 Journal of Combustion Science and Technology Jun.2014 DOII0.11715/rskxjs. R201403046 准东煤碱金属赋存形态及对燃烧特性的影晌 翁青松，王长安，车得福，付子文 (西安交通大学动力工程多相流国家重点实验室，西安 710049) 摘 要:实验研究了准东煤碱金属赋存形态以及不同萃取处理方式对其燃烧特性的影响.结果表明，准东煤的碱金 属纳含量明显高于其他煤种，而御的含量低于其他煤种 准东煤碱金属赋存形态与其他煤种差异很大，准东煤中的 碱金属铀主要以水溶性铀形式存在.经过不同萃取方式处理后的准东煤样燃烧的 DTG 曲线均明显向高温区偏移， 燃烧特性变差.萃取方式对准东煤样燃烧行为的影响存在显著差异，水溶性和有机形式的碱金属会对煤燃烧起到催 化作用. 关键词:准东煤:碱金属;赋存形态:燃烧特性 中图分类号: TK16 文献标志码:A 文章编号: 1006-8740(2014)03-0216-06 Alkali Metal Occurrence Mode and Its Influence on Combustion Characteristics in Zhundong Coals Weng Qingsong , Wang Changan , Che De旬， Fu Ziwen (State Key Laboratory of肌ifultiphase Flow for Power Engineering , Xian Jiaotong University , Xian 710049 , China) Abstract: In this paper , the occurrence mode of alkali metal in Zhundong coals has been experimentally sωdied. The effect of different extraction methods on combustion characteristics of Zhundong coals has also been investigated. Results show that the alkali metal Na in Zhundong coals is significantly higher than that in other types of coals , whereas the potassium content is lower. The occu汀ence mode of alkali metal in Zhundong coals is significantly differ- ent from that in other coals. Alkali metal Na in Zhundong coal mainly exists in the form of water soluble Na. After treating with the different extraction methods , the DTG curves of Zhundong coals move significantly towards that of the higher temperature zone , with combustion characteristics deteriorated. Different extraction methods have quite different influence on the