化学学士学位毕业论文——溶剂热微乳法制备纳米碳酸锶及其表征.docVIP

学 士 学 位 论 文 题目：溶剂热微乳法制备纳米碳酸锶及其表征 姓名 院系 专业 年级 学号 指导教师 年 月 日 溶剂热微乳法制备纳米碳酸锶及其表征 摘要：本文以硝酸锶碳酸铵为射线粉末衍射(XRD)、透射电镜(TEM)和傅立叶变换红外光谱对产物进行了表征。表明，℃条件外，不同条件下得到的碳酸锶粉体的晶型为斜方晶系；在= 20时，温度为室温、120℃样品是由近似球形颗粒组成温度150℃得到的产品为棒状结构温度对碳酸锶的形貌影响Research Progress of Microemulsion-Assisted Solvothermal Method for Preparing strontium carbonate Nanomaterials (School of Chemistry and Materials Science Ludong University Yantai 264025) Abstract Using strontium nitrate and ammonium carbonate as strontium and carbonate source, cetyl trimethyl ammonium bromide (CTAB)/n-butanol/H2O/heptane as solvent, SrCO3 nanomaterials were synthesized by Microemulsion-assisted solvothermal method. The effects of Wo (ratio of surfactant to cosurfactant) and reaction temperature on the structure and shape of crystals were mainly investigated. The purified SrCO3 crystals was characterized by X-ray diffraction (XRD), fourier transition infrared spectroscopy (FT-IR), and transmission electron microscope (TEM). The results showed that in adddition to the reaction temperature of 150℃, strontium carbonate nanomaterials synthesized under other condition were orthorhombic crystal, and when Wo was fixed as 20, the samples consisted of approximately spherical particles at room temperature and 120℃, and the rod-like structure were observed at 150℃, Which indicated the morphology of SrCO3 crystals were affected by the reaction temperature. Key Words Microemulsion-assisted solvothermal method; Strontium carbonate; Nanomaterials 目录1引言 1 1.1纳米碳酸锶的性质 1 1.2纳米碳酸锶的制备方法 1 1.3溶剂热微乳法 3 1.4溶剂热微乳法中影响纳米粒子制备的因素 4 1.5选题的目的和意义 6 2 实验部分 6 2.1实验仪器和试剂 6 2.2实验过程 7 3 结果与讨论 8 3.1 XRD分析 8 3.2 反应温度的影响 9 3.3红外光谱图分析 10 3.4 形貌分析 10 4 .结论 12 参考文献 12 1引言 纳米碳酸锶是21 世纪发展起来的新型纳米固体材料由于碳酸锶粒子达到纳米水平后其晶体的表面电子结构发生变化产生了大尺度碳酸锶不具有的新特性从而在电子工业、磁性材料、陶瓷釉及特种玻璃等许多领域有着更广泛的应用[1]。 1.1纳米碳酸锶 以纳米碳酸锶为添加剂制成的样品具有十分优异的性能如高磁导率、低损耗、高饱和磁化强度等性质可应用于开关电源、变压器、传感器、电容器、扬声器、阻尼器件、磁印刷等可实现器件的微型化、轻型化、高频化以及多功能化[2]。用纳米碳酸锶制备彩色显象管由于纳米碳酸锶具有很强的吸收X射线的能力在0.33~0.77范围内能有效地隔绝放射线还能显著改