油溶性导电聚苯胺的制备及其在固体电容器中的应用.pdfVIP

摘 要 种有机磺酸共掺杂的三种导电聚苯胺，研究了聚苯胺的电导率在高温 环境中的稳定性。发现氧气的存在是导致聚苯胺电导率剧烈衰减的重 要因素，在稀氧环境中能有效抑制聚苯胺电导率的衰减速度。进一步 利用 X 射线衍射分析了聚苯胺的有序化程度，结果表明，十二烷基 苯磺酸与樟脑磺酸的共掺杂不利于聚苯胺分子链的有序排列，使其电 导的热稳定性较差。 3.本文以 PANI-DBSA 溶液为浸渍液，探索了电容器的浸渍和老 练工艺，结果表明通过多次浸渍和预修复的方法可取得良好的效果， 所制备了 PANI 固体铝电解电容器具有高容量、低损耗角正切、优异 的温度特性、低漏电流且无漏电流回升等优点。另外，本文首次尝试 研制中高压固体电解电容器，所制备的固体电容器具备较高的耐受电 压，100V 时其漏电流只有 0.3 μA 。同时，高温稳定性实验表明，隔 离氧气的可以非常有效地减缓 PANI 固体铝电解电容器性能的衰减， 因此，在实际应用中对电容器进行密封包装显得十分重要。 关键词：聚苯胺；十二烷基苯磺酸；微乳液聚合；油溶性；导电；铝 电解电容器 II ABSTRACT ABSTRACT In many conductive polymer materials,many excellent performances are exhibited by polyaniline, such as lower price, simple synthetic method, high conductivity and potential processing characteristics. As conductive polyanilin was applied in solid aluminum electrolytic capacitors, many problems of liquid aluminum electrolytic capacitors,for instance, poor low temperature characteristics, high impedance in high frequency, leaking and drying out of electrolyte, would be smoothly solved, furthermore, the essential properties of the aluminum electrolytic capacitors would be improved greatly.Therefore, the broad prospects of its application in electrolytic capacitors have been attracting much interest in its synthesis, preparation and processing. In this project, oil-soluble conductive polyaniline was synthesized by microemulsion method with dodecylbenzene sulfonate(DBSA) as dopant. To ensure conductivity and solubility, washing and centrifugal separation method were established to removal the residual DBSA. Moreover, structure and