熔融还原法镍渣炼铁的热力学与动力学.pdfVIP

3 2 Vol. 3 No. 2 2009 2 Journal of University of Science and Technology Beijing Feb. 2009 倪 文 马明生 王亚利 王中杰 刘凤梅 , 100083 , . XRD FeOSiO . FeOSiO , 2 2 , . CaO . 1450~ 1600 Gibbs , ( FeO) + C( S) [ Fe] + CO . : 100 gCaO 34 gCaF 404 g 85 g; 1500 180 min. 2 , 9632% . ; ; ; TF 135 Thermodynamic and kinetic in recovery of iron from nickel residue N I Wen, MA M ing-sheng , WA N G Ya-li, WA N G Zhong-j ie, L I U Feng-mei Key Laboratory of the Ministry of E ducation of China for High-Efficient Mining and Safety of Metal Mines, University of Science and Technology Be-i jing, Beijing 100083, China ABSTRACT A study of extracting iron from nickel residue was done by smelting reduction method. The experiments were conduct- ed to investigate the effect of slag basicity, melting t ime and temperature on t he iron recovery ratio . XRD analysis indicates that the nickel residue is composed of FeSiO and glassy silicates, so it is impossible to reach the target of FeO content by regular ore-dressing 3 method except by smelting reduction method. Experimental results show that the recovery rat io of iron increases with increasing the content of CaO added, melting temperature and time. The key reduction react ion is firmed as ( FeO) + C( S) [ Fe] + CO by comparing Gibbs free energies at different temperatures from 1450 to 1600 . The batch of nickel residue 100g, CaO 34 g, CaF2 404 g and coke 85g w as the best formula in this study , and it was indicated that after melting at 1500 for 180 min, the slag and iron w ere w ell separated and the recovery ratio w as up to 9632% for this batch. KEY WORDS slag basicity ; melting reduction; nickel residue; recovery ratio