摘要 - 环境工程学报.DOCVIP

（编辑修改稿，稿件编号：201504109） 低分子有机酸对染料废水电催化氧化的影响 李萌1马宏瑞1张乾隆1王景平2花莉1 陕西科技大学资源与环境学院，西安7100212. 陕西科技大学化学与化工学院，西安 710021） 研究了二维模式下，形稳性阳极Dimension stable anode, DSA)作为电极材料处理以不同比例混合的酸性大红3RAcid Red 3R, 3R) 与草酸（Oxalic acid，OA）模拟废水。通过CODCr、TOC测定和紫外-可见光谱分析等手段可以得出，10mA/cm2，明显低于3R电解时所需的电流密度25mA/cm2 关键词 染料废水酸性大红3R降解 Effect?of?low?molecular?oganic?acids?on?electrocatalytic? oxidation?of?dye?wastewater Li Meng1 Ma Hongrui1 Zhang Qianlong1 Wang Jingping2 Hua Li1 College of Resource and Environment, Shaanxi University of Science and Technology, Xi’an 710021，China； 2.College?of?Chemistry?and?Chemical?Engineering, Shaanxi University of Science and Technology, Xi’an 710021，China) Abstract The dimension stable anode (DSA) was used as the electrode material to handle simulated wastewater of Acid Red 3R (3R) and oxalic acid (OA) mixed in different proportions in the 2D mode. According to results of CODCr, TOC, ulrte-visible spectroscopy, as well as electrochemical?measurements, it can be concluded that the current density required for OA in electrocatalytic degradation was 10mA/cm2, which was significantly lower than that of the 3R, 25mA/cm2. In the electrocatalytic degradation of mixed dye wastewater, electrolysis can effectively decompose the chromophore on dye, and the degradable organic component OA would be oxidized with priority which would improve the removal efficiency of refractory organic component 3R. In addition, the wastewater pH can cause differences of electrocatalytic mechanism . When the pH is low, cathodic hydrogen evolution reaction dominates so pH is elevated and when it is high,Cl2 is produced by the chlorine reaction of the anode, which formed H3O+ by the hydrolysis，while organic component?is oxidized?organic?acid,?due to the?pH decreasing. Key words dyes wastewater；acid Red 3R；degradation 合成染料废水具有浓度高、盐份高、色度大、难生物降解、组分复杂等特点，使其处理一直是个难题[1-2]。现有染料废水的处理方式主要由物化法、生物法的组合工艺构成，其中物化预处理过程是系统良好运行的关键[3-5]。为解决高毒性、难降解的问题，各种高级氧化技术(advanced oxidation processes，AOPs)受到越来越多的重视[