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PHYSICAL REVIEW B VOLUME 53, NUMBER 17 1 MAY 1996-I Relaxational and vibrational dynamics in the glass-transition range of a strong glass former B2 O3 * ¨ A. Brodin, L. Borjesson, D. Engberg, and L. M. Torell ¨ Department of Physics, Chalmers University of Technology, S-412 96 Goteborg, Sweden A. P. Sokolov† ¨ Max-Planck-Institut fur Polymerforschung, D-55021 Mainz, Germany Received 26 May 1995 The structural relaxation behavior of a strong glass former B 2 O 3 has been investigated over broad tempera- ture 300–1275 K and frequency 0.5 GHz–10 THz ranges using depolarized light scattering. The spectra clearly show nonmonotonic temperature behavior with some dynamical crossover at about Tc 800– 900 K. Above Tc the spectra develop qualitatively according to the general scenario predicted by the mode-coupling theory MCT, including a fast process and a much slower process in addition to a vibrational contribu- tion. However, there is disagreement between the observed functional form of the fast relaxational dynamics and that predicted by MCT. The disagreement seems to be related to the influence of low-lying vibrational contributions, the