转炉终点钢水残锰含量及其影响因素分析论文.docVIP

转炉终点钢水残锰含量及其影响因素分析 杨传信1、1，2、（1.临沂华盛江泉管业有限公司，山东，临沂 276017；2.武汉科技大学 · 钢铁冶金及资源利用省部共建教育部重点实验室，湖北，武汉430081） esidual Manganese Content in Molten Steel of End-point of BOF Operation and its influencing factors YANG Chuanxin1,LI Pengchao1,2, XUE Zhengliang2, LU Zhaojun2, LIU Qiang2, LI Ping1 1. Linyi Huasheng Jiangquan Pipes Co., Ltd., Linyi 276017; 2. Key Laboratory for Ferrous Metallurgy and Resources Utilization of Ministry of Education, Wuhan University of Science and Technology, Wuhan 430081 ABSTRACT: Through the statistical analysis to the production data of end-point of BOF and the contents of molten iron, the factors affected end-point residual content of manganese of BOF and its law have been researched, which has illustrated that the end point carbon content of BOF and initial silicon content of molten iron are the key factors for end-point residual content of manganese and its yield rate. It’s disadvantageous for raising the basicity and FeO content of end slag of BOF to end-point residual content of manganese and its yield rate. Raising the manganese content of molten iron could increase the residual manganese content at end-point of BOF, but decrease its yield rate. The end temperature of molten steel in BOF is unessential to the yield rate of manganese. KEY WORDS：BOF, end-point residual content of manganese, end-point control 提高转炉钢水终点残锰含量是降低炼钢生产成本的重要手段，近年来国内许多钢厂开展了在转炉中加锰矿的“锰矿直接合金化”工业试验研究[1~4]，旨在提高转炉终点残锰含量，降低炉后合金化用锰铁单耗。临沂华盛江泉管业有限公司2008年9月投产120t顶底复吹转炉120tLF精炼炉八机八流合金钢连铸机生产优质碳素管坯钢，年产钢坯160万吨，棒材140万吨华盛江泉管业有限公司采用BOF-工艺生产优质碳素管坯钢（C 0.~0.23%、Si 0.1~0.37%、Mn 0.~0.65%、P≤0.0%、S≤0.0%），120t转炉装入铁水1t +生铁15T+废钢1t，采用渣高拉碳工艺，石灰及白云石加入量5kg/t，吹氧12min左右倒炉取样，终点控制目标：R=3.～.0、C=0.%~0.17%、P、S0.025%、温度16℃～16℃。保证红包出钢，出钢时必须加挡渣球，当钢水出来1/5后，顺序加入硅锰、，出钢3/4~4/5时堵挡渣塞，转炉下渣厚度控制在50mm以下，炉后。 J/mol （1） 吹炼中期，随着熔池温度升高，钢水脱碳反应加速，前期被氧化进入渣中的MnO部分按式（2）还原重新返回钢液。 J/mol （2） 吹炼后期，随着钢水碳含量下降，钢水和炉渣的氧化性大大增加，钢水中的锰按式（3）和式（4）被重新氧化进入炉渣。