电工模塑料用结晶不饱和聚酯的性能研究.docVIP

电工模塑料用不饱和聚酯的雷圆吕建(胡舒龙卢凤英（桂林理工大学，有色金属及材料加工新技术教育部重点实验室，广西桂林541004） 摘 要：以对苯二甲酸，反丁烯二酸，乙二醇，1,4-丁二醇为主要原料，合成了四种不饱和聚酯，产物经、，研究了复合材料的性能，与国内外进行对比。结果表明，当配比为n(对苯二甲酸)：n(反丁烯二酸)：n(乙二醇)：n（1,4-丁二醇）=1.3:1:0.69:1.61时，软化点，为101～106℃复合材料的冲击强度和弯曲强度为6.61 KJ/m2和97.62 MPa，热变形温度为226℃，满足电工模塑料制品性能要求关键字不饱和聚酯电工模塑料性能Study on the Properies of Crystalline Unsaturated Polyester for Electrical Moulding Material LEI Yuan，LV Jian(，HU Shulong，LU Fengying，ZHANG Zhen (Key Laboratory of new processing Technology for Nonferrous Metals and Materials, Ministry of Education, Guilin University of Technology, Guilin , Guangxi, 541004) Abstract: The four Crystalline Unsaturated Polyester were synthesized form terephthalic acid, fumaric acid, ethylene glycol, 1,4-Butanediol as the main materials. The final products were characterized by means of Polarizing Microscope(POM), X-ray diffraction(XRD), then the thermal-mechanical properties and electrical properties of the composites were studied. The results showed that the best molar rations of Unsaturated Polyester raw materials terephthalic acid, fumaric acid, ethylene glycol,1,4-ButanedIol were 1.3:1:0.69:1.61, the Unsaturated Polyester has a good crystalline performance and the softening point is better suitable ,it is 101～106solved the problem of Unsaturated Polyester is easy to agglomerate and easy to sticky at normal temperature; The composite was detected to has good properties with 6.61 KJ/m2 of the impact strength and 97.62 MPa of the flexural strength, and 226℃ of the heat distortion temperature, which met the performance requirements of the Electrical Moulding Compound, and achieved the level of similar products at abroad. Key words: Crystalline Unsaturated Polyester；Electrical Moulding Compound；Properties 0 引言 干式不饱和聚酯塑料具有优良的综合性能，固化时间短，生产效率高，环保等优点，航空电连接器、继电器元件等微型低压电器元件。与BMC、SMC相比，干式不饱和聚酯存储期较长，约为BMC、SMC的2~3倍[1]，因此备受市场睐。但传统干式不饱和聚酯软化点较低，一般~80℃，常温存储和运输过程中存在易结块，操作易粘手等缺点，因此制备具有高软化点的干式不饱和聚酯仍然具有重要意义。 研究发现[2]，引入多元醇，对称性长链二元酸或二元醇可提高结晶性，提高软化点黄志雄[3]等合成了新戊二醇型SMC用结晶不饱和聚酯，可