Al-Zn-In牺牲阳极在不同工作电流密度下电流效率及溶解机制的研究.PDFVIP

1期 69 Al-Zn-In 牺牲阳极在不同工作电流密度下电流 效率及溶解机制的研究 赵国强 魏英华 李 京 中国科学院金属研究所金属腐蚀与防护国家重点实验室 沈阳 110016 摘要：采用电化学方法测定了Al-Zn-In 牺牲阳极在不同工作电流密度下的电流效率和溶解机制。结果表明， 工作电流密度的变化会引起Al-Zn-In 牺牲阳极溶解机制发生改变，从而引起电流效率发生变化。在较小的工 作电流密度下，Al-Zn-In 牺牲阳极的电流效率异常降低，其原因可能是In3+ 和Zn2+ 等离子的再沉积过程受到抑 制，使Al-Zn-In 牺牲阳极表面形成一层氧化膜。氧化膜的破裂和溶解过程不会产生电流，而能引起牺牲阳极 的质量损耗，导致阳极电流效率小于理论值。 关键词：Al-Zn-In 牺牲阳极 工作电流密度 电流效率 溶解机制 中图分类号：TG 174.1 文献标识码：A 文章编号：1005-4537(2015)01-0000-06 Current Efficiency and Corrosion Mechanism of Al-Zn-In Sacrificial Anode at Different Current Densities ZHAO Guoqiang, WEI Yinghua, LI Jing State Key Laboratory for Corrosion and Protection, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China Abstract: The current efficiency and corrosion mechanism of Al-Zn-In sacrificial anode by differ- ent impressed current densities were investigated by using electrochemical methods. Results showed that the corrosion mechanism and the current efficiency of the Al-Zn-In sacrificial anode varied with the impressed current densities. The current efficiency decreases dramatically by a low current density, this may be caused by the fact that the re-deposition of the dissolved cations (In3 + , Zn2 + ) was suppressed and an oxides film might formed on the alloy surface. A mass loss of the an- ode might be caused by the cracking and dissolving of the oxides film, and this might be responsi- ble to the current efficiency of Al-Zn-In sacrificial anode lower than that theoretically expected by the low impressed current density. Key words: Al-Zn-In sacrificial anode, working current density, current efficiency, corrosion