二氧化钛光催化降解有机污染物的性能试卷.doc

二氧化钛光催化降解有机污染物的性能研究 摘 要 关键词  Properties of organic pollutants Photocatalytic Degradation ABSTRACT In this paper, titanium dioxide was prepared by hydrothermal method to prepare rutile titanium dioxide nanorods by using four butyl titanate as titanium source. On the basis of this study, the photocatalytic degradation of methylene blue under infrared light is studied. And through the adjustment of the experimental conditions such as temperature, pH, the amount of photocatalyst, it was concluded that the relative optimum conditions of photocatalytic degradation of methylene blue were obtained. In addition, by X-ray diffraction, cyclic voltammetry and scanning electron microscope (SEM) method of TiO2 nano meter sticks from the phase and microstructure were characterized. The experimental results show that the room temperature and for 40mg / mL of methylene blue solution, adding more than 1.0g of TiO2 photocatalytic degradation catalyst reaction 20MIN can achieve 89% of the degradation rate, but with the amount of catalyst increase and decrease, the degradation efficiency of catalyst will reduce, so the photocatalytic degradation should pay attention to the usage of catalyst, should not be too much, also should not be too little. Keywords Rutile Titanium Dioxide hydrothermal Photocatalytic Degradation of methylene blue  目 录 一 绪论 1 1.1 前言 1 1.2 纳米TiO2催化剂合成 2 1.2.1气相法 2 1.2.2 液相法 3 1.2.3 水热法 5 1.2.4 纳米TiO2的微观结构 6 光催化降解原理 7 1.3纳米TiO2在废水处理上的应用 8 1.3.1含油废水 8 1.3.2制药废水 9 1.3.3印染废水 9 1.3.4造纸废水 9 1.3.5表面活性剂废水 9 1.3.6垃圾渗滤液 10 1.3.7重金属废水 10 1.3.8无机非金属废水 10 1.4 本文的研究意义，目的以及内容 10 第章 实验部分 12 2.1实验药品与仪器 12 2.2 TiO2的合成与制备 12 2. TiO2光催化 13 2.3.1 实验装置的搭建 13 2..2亚甲基蓝光催化降解实验 14 第章 实验结果与讨论 16 .1TiO2的结构表征 16 .1 X-射线衍射（XRD） 16 3.1.2扫描电镜（SEM） 16 3. 亚甲基蓝的标准曲线 17 3.2不同温度下亚甲基蓝的降解情况 18 3.3不同催化剂浓度下亚甲基蓝的降解率 19 3.4 实验体会 19 结论 20 致谢 21 参考文献 22   一 绪论 1.1 前言 随着染料产业方面的迅速发展，工业染料所产生的废水对自然环境造成的污染已成为人们必须解决的严峻问题。废水中的污染物由于物质结构，性质稳定难以进行的降解。亚甲基蓝是一种应用广泛的工业染料，且传统的降解处理方式难以对亚甲基